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Determining the predominant tautomeric structure of iodine-based group-transfer reagents by (17)O NMR spectroscopy
Cyclic benziodoxole systems have become a premier scaffold for the design of electrophilic transfer reagents. A particularly intriguing aspect is the fundamental I(I)–I(III) tautomerism about the hypervalent bond, which has led in certain cases to a surprising re-evaluation of the classic hypervalen...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6122331/ https://www.ncbi.nlm.nih.gov/pubmed/30202482 http://dx.doi.org/10.3762/bjoc.14.203 |