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Determining the predominant tautomeric structure of iodine-based group-transfer reagents by (17)O NMR spectroscopy

Cyclic benziodoxole systems have become a premier scaffold for the design of electrophilic transfer reagents. A particularly intriguing aspect is the fundamental I(I)–I(III) tautomerism about the hypervalent bond, which has led in certain cases to a surprising re-evaluation of the classic hypervalen...

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Detalles Bibliográficos
Autores principales:	Santschi, Nico, Pitts, Cody Ross, Jelier, Benson J, Verel, René
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2018
Materias:	Full Research Paper
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6122331/ https://www.ncbi.nlm.nih.gov/pubmed/30202482 http://dx.doi.org/10.3762/bjoc.14.203

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