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Cobalt bis(acetylacetonate)–tert-butyl hydroperoxide–triethylsilane: a general reagent combination for the Markovnikov-selective hydrofunctionalization of alkenes by hydrogen atom transfer

We show that cobalt bis(acetylacetonate) [Co(acac)(2)], tert-butyl hydroperoxide (TBHP), and triethylsilane (Et(3)SiH) constitute an inexpensive, general, and practical reagent combination to initiate a broad range of Markovnikov-selective alkene hydrofunctionalization reactions. These transformatio...

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Detalles Bibliográficos
Autores principales:	Ma, Xiaoshen, Herzon, Seth B
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2018
Materias:	Full Research Paper
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6122341/ https://www.ncbi.nlm.nih.gov/pubmed/30202480 http://dx.doi.org/10.3762/bjoc.14.201

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