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H-bonded reusable template assisted para-selective ketonisation using soft electrophilic vinyl ethers
In nature, enzymatic pathways generate C(aryl)−C(O) bonds in a site-selective fashion. Synthetically, C(aryl)−C(O) bonds are synthesised in organometallic reactions using prefunctionalized substrate materials. Electrophilic routes are largely limited to electron-rich systems, non-polar medium, and m...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6123475/ https://www.ncbi.nlm.nih.gov/pubmed/30181575 http://dx.doi.org/10.1038/s41467-018-06018-2 |