Crystal structure of Ti(8)Bi(9)O(0.25) containing inter­stitial oxygen atoms

Single crystals of Ti(8)Bi(9)O(0.25), titanium bis­muth oxide (8/9/0.25), were obtained from a sample prepared by heating a mixture of Ti, TiO(2) and Bi powders in an Ar atmosphere. Single-crystal X-ray analysis revealed that the introduction of O atoms into the structure of Ti(8)Bi(9) retains the s...

Descripción completa

Detalles Bibliográficos
Autores principales: Yamane, Hisanori, Hiraka, Keita
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6127688/
https://www.ncbi.nlm.nih.gov/pubmed/30225133
http://dx.doi.org/10.1107/S205698901801188X
Descripción
Sumario:Single crystals of Ti(8)Bi(9)O(0.25), titanium bis­muth oxide (8/9/0.25), were obtained from a sample prepared by heating a mixture of Ti, TiO(2) and Bi powders in an Ar atmosphere. Single-crystal X-ray analysis revealed that the introduction of O atoms into the structure of Ti(8)Bi(9) retains the space-group type P4/nmm. The oxygen site is located within a Ti(4) tetra­hedron (point group symmetry [Image: see text] m2) that is vacant in the Ti(8)Bi(9) crystal structure. The occupancy of this site is 0.25 (4), and the O—Ti distance is 1.8824 (11) Å.

Ejemplares similares