Crystal structure of Ti(8)Bi(9)O(0.25) containing inter­stitial oxygen atoms

Single crystals of Ti(8)Bi(9)O(0.25), titanium bis­muth oxide (8/9/0.25), were obtained from a sample prepared by heating a mixture of Ti, TiO(2) and Bi powders in an Ar atmosphere. Single-crystal X-ray analysis revealed that the introduction of O atoms into the structure of Ti(8)Bi(9) retains the s...

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Detalles Bibliográficos
Autores principales: Yamane, Hisanori, Hiraka, Keita
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6127688/
https://www.ncbi.nlm.nih.gov/pubmed/30225133
http://dx.doi.org/10.1107/S205698901801188X
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author Yamane, Hisanori
Hiraka, Keita
author_facet Yamane, Hisanori
Hiraka, Keita
author_sort Yamane, Hisanori
collection PubMed
description Single crystals of Ti(8)Bi(9)O(0.25), titanium bis­muth oxide (8/9/0.25), were obtained from a sample prepared by heating a mixture of Ti, TiO(2) and Bi powders in an Ar atmosphere. Single-crystal X-ray analysis revealed that the introduction of O atoms into the structure of Ti(8)Bi(9) retains the space-group type P4/nmm. The oxygen site is located within a Ti(4) tetra­hedron (point group symmetry [Image: see text] m2) that is vacant in the Ti(8)Bi(9) crystal structure. The occupancy of this site is 0.25 (4), and the O—Ti distance is 1.8824 (11) Å.
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spelling pubmed-61276882018-09-17 Crystal structure of Ti(8)Bi(9)O(0.25) containing inter­stitial oxygen atoms Yamane, Hisanori Hiraka, Keita Acta Crystallogr E Crystallogr Commun Research Communications Single crystals of Ti(8)Bi(9)O(0.25), titanium bis­muth oxide (8/9/0.25), were obtained from a sample prepared by heating a mixture of Ti, TiO(2) and Bi powders in an Ar atmosphere. Single-crystal X-ray analysis revealed that the introduction of O atoms into the structure of Ti(8)Bi(9) retains the space-group type P4/nmm. The oxygen site is located within a Ti(4) tetra­hedron (point group symmetry [Image: see text] m2) that is vacant in the Ti(8)Bi(9) crystal structure. The occupancy of this site is 0.25 (4), and the O—Ti distance is 1.8824 (11) Å. International Union of Crystallography 2018-08-24 /pmc/articles/PMC6127688/ /pubmed/30225133 http://dx.doi.org/10.1107/S205698901801188X Text en © Yamane and Hiraka 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Yamane, Hisanori
Hiraka, Keita
Crystal structure of Ti(8)Bi(9)O(0.25) containing inter­stitial oxygen atoms
title Crystal structure of Ti(8)Bi(9)O(0.25) containing inter­stitial oxygen atoms
title_full Crystal structure of Ti(8)Bi(9)O(0.25) containing inter­stitial oxygen atoms
title_fullStr Crystal structure of Ti(8)Bi(9)O(0.25) containing inter­stitial oxygen atoms
title_full_unstemmed Crystal structure of Ti(8)Bi(9)O(0.25) containing inter­stitial oxygen atoms
title_short Crystal structure of Ti(8)Bi(9)O(0.25) containing inter­stitial oxygen atoms
title_sort crystal structure of ti(8)bi(9)o(0.25) containing inter­stitial oxygen atoms
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6127688/
https://www.ncbi.nlm.nih.gov/pubmed/30225133
http://dx.doi.org/10.1107/S205698901801188X
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