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X-ray structure analysis of symmetrically substituted 1,1′-diformylruthenocene
1,1′-Diformylruthenocene, [Ru(C(6)H(5)O)(2)], crystallizes in the orthorhombic system in the P2(1)2(1)2(1) space group at room temperature. There are two crystallographically independent molecules in the asymmetric unit. The cyclopentadienyl rings have eclipsed configuration. The molecules s...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6127689/ https://www.ncbi.nlm.nih.gov/pubmed/30225096 http://dx.doi.org/10.1107/S2056989018010642 |
Sumario: | 1,1′-Diformylruthenocene, [Ru(C(6)H(5)O)(2)], crystallizes in the orthorhombic system in the P2(1)2(1)2(1) space group at room temperature. There are two crystallographically independent molecules in the asymmetric unit. The cyclopentadienyl rings have eclipsed configuration. The molecules self-assemble in a two-dimensional structure by C—H⋯O and C—H⋯π interactions with cisoid relative orientations of the two formyl groups. The crystal studied was refined as an inversion twin. |
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