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Crystal structure and redox potentials of the tppz-bridged {RuCl(bpy)}(+) dimer

We report the structural and electrochemical characterization of the binuclear complex [μ-(C(24)H(16)N(6)){RuCl(C(10)H(8)N(2))}(2)](PF(6))(2), which contains the bis-tridentate bridging ligand 2,3,5,6-tetra­kis­(pyridin-2-yl)pyrazine (tppz), the monodentate ligand Cl(−), and the bidentate ligand 2,2...

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Detalles Bibliográficos
Autores principales: Rein, Francisca N., Chen, Weizhong, Scott, Brian L., Rocha, Reginaldo C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6127700/
https://www.ncbi.nlm.nih.gov/pubmed/30225110
http://dx.doi.org/10.1107/S2056989018011258