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Crystal structure of fac-bis[bis(pyridin-2-yl)methanamine]iron(II) 1,1,3,3-tetracyano-2-(dicyanomethylidene)propane-1,3-diide, [Fe(dipa)(2)](tcpd)
In the title compound, [Fe(C(11)H(11)N(3))(2)](C(10)N(6)), the Fe(II) cation is coordinated by two bis(pyridin-2-yl)methanamine (dipa) ligands and has crystallographic twofold symmetry. There are deviations from ideal octahedral geometry due to the steric requirements of the ligands. The polynitril...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6127702/ https://www.ncbi.nlm.nih.gov/pubmed/30225105 http://dx.doi.org/10.1107/S2056989018011143 |
Sumario: | In the title compound, [Fe(C(11)H(11)N(3))(2)](C(10)N(6)), the Fe(II) cation is coordinated by two bis(pyridin-2-yl)methanamine (dipa) ligands and has crystallographic twofold symmetry. There are deviations from ideal octahedral geometry due to the steric requirements of the ligands. The polynitrile 1,1,3,3-tetracyano-2-(dicyanomethylidene)propane-1,3-diide (tcpd(2−)) dianion is disordered about an inversion center and is not coordinated to the Fe atom. The anion is not planar but has a propeller shape. In the crystal, weak N—H⋯N interactions between the amine H atoms of the dipa ligands and two nitrile groups of the anion form an alternating chain of cations and anions related by the C-centering of the unit cell. |
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