Crystal structure of the [(1,3-dimesityl-1H-imidazol-3-ium-2-yl)methano­lato]copper(II) chloride dimer: insertion of formaldehyde into a copper–carbene bond

The crystal structure of bis­[μ-(1,3-dimesityl-1H-imidazol-3-ium-2-yl)methano­lato-κ(2) O:O]bis­[di­chlorido­copper(II)], [Cu(2)Cl(4)(C(22)H(26)N(2)O)(2)], is reported. The complex is assumed to have formed via the insertion of formaldehyde into the copper–carbon bond in an N-heterocyclic carbene co...

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Detalles Bibliográficos
Autores principales: Dodds, Christopher A., Kennedy, Alan R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6127712/
https://www.ncbi.nlm.nih.gov/pubmed/30225134
http://dx.doi.org/10.1107/S205698901801201X

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6127712/
https://www.ncbi.nlm.nih.gov/pubmed/30225134
http://dx.doi.org/10.1107/S205698901801201X

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