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Crystal structure of the [(1,3-dimesityl-1H-imidazol-3-ium-2-yl)methanolato]copper(II) chloride dimer: insertion of formaldehyde into a copper–carbene bond

The crystal structure of bis[μ-(1,3-dimesityl-1H-imidazol-3-ium-2-yl)methanolato-κ(2) O:O]bis[dichloridocopper(II)], [Cu(2)Cl(4)(C(22)H(26)N(2)O)(2)], is reported. The complex is assumed to have formed via the insertion of formaldehyde into the copper–carbon bond in an N-heterocyclic carbene co...

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Detalles Bibliográficos
Autores principales:	Dodds, Christopher A., Kennedy, Alan R.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	International Union of Crystallography 2018
Materias:	Research Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6127712/ https://www.ncbi.nlm.nih.gov/pubmed/30225134 http://dx.doi.org/10.1107/S205698901801201X

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