Cargando…

Metal-free alkene oxy- and amino-perfluoroalkylations via carbocation formation by using perfluoro acid anhydrides: unique reactivity between styrenes and perfluoro diacyl peroxides

We present a strategy for metal-free, alkene difunctionalization-type, oxy- and amino-perfluoroalkylations, using perfluoro acid anhydrides as practical and user-friendly perfluoroalkyl sources. This method provides efficient access to oxy-perfluoroalkylation products via carbocation formation due t...

Descripción completa

Detalles Bibliográficos
Autores principales:	Valverde, Elena, Kawamura, Shintaro, Sekine, Daisuke, Sodeoka, Mikiko
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6137437/ https://www.ncbi.nlm.nih.gov/pubmed/30310632 http://dx.doi.org/10.1039/c8sc02547a

Ejemplares similares

Perfluoro Alkyl Hypofluorites and Peroxides Revisited
por: Nissen, Jan H., et al.
Publicado: (2019)

Perfluoro-n-octane mimicking an intraocular foreign body
por: Baskaran, Prabu, et al.
Publicado: (2017)

Reversible Corneal Toxicity of Retained Intracameral Perfluoro-n-octane
por: Alharbi, Saad S., et al.
Publicado: (2016)

Synthesis of Polyfluorinated Thia- and Oxathiacalixarenes Based on Perfluoro-m-xylene
por: Kovtonyuk, Vladimir N., et al.
Publicado: (2021)

Investigation of Bis(Perfluoro‐tert‐Butoxy) Halogenates(I/III)
por: Pröhm, Patrick, et al.
Publicado: (2021)

The Perfluoro Cage Effect: A Search for Electron-Encapsulating Molecules
por: Ghosh, Abhik, et al.
Publicado: (2023)

Effect of end group of amorphous perfluoro-polymer electrets on electron trapping
por: Kim, Seonwoo, et al.
Publicado: (2018)

Endocrine disruption of vitamin D activity by perfluoro-octanoic acid (PFOA)
por: Di Nisio, Andrea, et al.
Publicado: (2020)

Vitreous inflammation and macular edema secondary to perfluoro-n-octane toxicity
por: Rodríguez-González, Fayna, et al.
Publicado: (2021)

Short-term postoperative perfluoro-n-octane tamponade for pediatric recurrent retinal detachment
por: Ling, Kiet-Phang, et al.
Publicado: (2018)

Perfluoro Allyl Fluorosulfate (FAFS): A Versatile Building Block for New Fluoroallylic Compounds
por: Wlassics, Ivan, et al.
Publicado: (2011)

Synthesis of Tailored Perfluoro Unsaturated Monomers for Potential Applications in Proton Exchange Membrane Preparation
por: Monopoli, Antonio, et al.
Publicado: (2021)

Ocular tolerance and efficacy of short-term tamponade with double filling of polydimethyloxane and perfluoro-n-octane
por: Zenoni, Stefano, et al.
Publicado: (2011)

Crystal structures and Hirshfeld surface analysis of a series of 4-O-arylperfluoropyridines
por: Peloquin, Andrew J., et al.
Publicado: (2019)

Impact of Perfluoro and Alkylphosphonic Self-Assembled Monolayers on Tribological and Antimicrobial Properties of Ti-DLC Coatings
por: Cichomski, Michal, et al.
Publicado: (2019)

Retinal detachment repair with perfluoro-N-octane endotamponade in an infant with juvenile X-linked retinoschisis
por: Chiang, Homer, et al.
Publicado: (2020)

Product Control in Alkene Trifluoromethylation: Hydrotrifluoromethylation, Vinylic Trifluoromethylation, and Iodotrifluoromethylation using Togni Reagent
por: Egami, Hiromichi, et al.
Publicado: (2015)

Increased Cardiovascular Risk Associated with Chemical Sensitivity to Perfluoro–Octanoic Acid: Role of Impaired Platelet Aggregation
por: De Toni, Luca, et al.
Publicado: (2020)

Exposure to Perfluoro-Octanoic Acid Associated With Upstream Uncoupling of the Insulin Signaling in Human Hepatocyte Cell Line
por: De Toni, Luca, et al.
Publicado: (2021)

Legacy perfluoro-alkyl substances impair LDL-cholesterol uptake independently from PCSK9-function
por: Sabovic, Iva, et al.
Publicado: (2023)

Perfluoro-n-octane as a temporary intraocular tamponade in a staged approach to manage complex retinal detachments
por: Barthelmes, Daniel, et al.
Publicado: (2015)

Perfluoro-n-octane-assisted mega Weiss-ring technique for posterior vitreous detachment induction in retinal detachment
por: Babu, Naresh, et al.
Publicado: (2019)

PFOh No: Spontaneous Globe Rupture During Injection of Perfluoro-n-Octane (PFO) During Retinal Detachment Repair
por: Hammer, Jon David, et al.
Publicado: (2020)

Nine Years of Retained Perfluoro-n-octane in the Anterior Chamber after Retinal Detachment Repair with No Signs of Ocular Toxicity
por: Abboud, Emad B., et al.
Publicado: (2014)

On the Question of Zwitterionic Intermediates in the [3 + 2] Cycloaddition Reactions between C-arylnitrones and Perfluoro 2-Methylpent-2-ene
por: Mitka, Katarzyna, et al.
Publicado: (2021)

Synthesis, crystal structure and Hirshfeld surface analysis of 2-(perfluorophenyl)acetamide in comparison with some related compounds
por: Novikov, Anton P., et al.
Publicado: (2022)

An Experimental Study on Antioxidant Enzyme Gene Expression in Trematomus newnesi (Boulenger, 1902) Experimentally Exposed to Perfluoro-Octanoic Acid
por: Pacchini, Sara, et al.
Publicado: (2023)

Recent Advances on the Halo- and Cyano-Trifluoromethylation of Alkenes and Alkynes
por: Fu, Bo, et al.
Publicado: (2021)

4,4′-[4,4′-(Perfluoropropane-2,2-diyl)bis(4,1-phenyleneoxy)]dianiline
por: Nawaz, Haq, et al.
Publicado: (2009)

[1,3-Bis(diphenylphosphino)propane-κ(2) P,P′]diiodido(perfluoropropyl)rhodium(III) dichloromethane solvate
por: Panthi, Basu, et al.
Publicado: (2008)

Role of Counterions in the Adsorption and Micellization Behavior of 1:1 Ionic Surfactants at Fluid Interfaces—Demonstrated by the Standard Amphiphile System of Alkali Perfluoro-n-octanoates
por: Lunkenheimer, Klaus, et al.
Publicado: (2022)

Fluorine-19 MRI at 21.1 T: enhanced spin–lattice relaxation of perfluoro-15-crown-5-ether and sensitivity as demonstrated in ex vivo murine neuroinflammation
por: Waiczies, Sonia, et al.
Publicado: (2018)

(2S,4R)- and (2S,4S)-Perfluoro-tert-butyl 4-Hydroxyproline: Two Conformationally Distinct Proline Amino Acids for Sensitive Application in (19)F NMR
por: Tressler, Caitlin M., et al.
Publicado: (2014)

A comparative study of the coordination behavior of cyclo-P(5) and cyclo-As(5) ligand complexes towards the trinuclear Lewis acid complex (perfluoro-ortho-phenylene)mercury
por: Fleischmann, Martin, et al.
Publicado: (2015)

Perfluoroalkylative pyridylation of alkenes via 4-cyanopyridine-boryl radicals
por: Cao, Jia, et al.
Publicado: (2019)

Sub-perfluoro-n-octane injection of ocular viscoelastic device assisted inverted internal limiting membrane flap for macular hole retinal detachment surgery: a novel technique
por: Lai, Chi-Chun, et al.
Publicado: (2020)

Exploring the Decomposition Products of 1,3,3,3-Tetrafluoropropene and Perfluoro-(3-methylbutan-2-one) Gas Mixtures in Medium-Voltage Electrical Switchgear as Alternatives to SF6
por: Alonso, María Luz, et al.
Publicado: (2021)

α-Perfluoroalkyl-β-alkynylation of alkenes via radical alkynyl migration
por: Tang, Xinjun, et al.
Publicado: (2017)

Hydroxy- and Hydro-Perfluoroalkylation of Styrenes by Controlling the Quenching Cycle of Eosin Y
por: Shibata, Haruko, et al.
Publicado: (2023)

Effect of Styrene-Maleic Anhydride Copolymer on Properties of PBST/PLA Blends
por: Zhang, Qing, et al.
Publicado: (2023)

Cannot write session to /tmp/vufind_sessions/sess_39sgu1hhj4m7lekqfrgfajdi77