Facile and systematic access to the least-coordinating WCA [(R(F)O)(3)Al–F–Al(OR(F))(3)](–) and its more Lewis-basic brother [F–Al(OR(F))(3)](–) (R(F) = C(CF(3))(3))

By reaction of the Lewis acid Me(3)Si–F–Al(OR(F))(3) with a series of [PF(6)](–) salts, gaseous PF(5) and Me(3)Si–F are liberated and salts of the anion [F–Al(OR(F))(3)](–) ([f–al](–); R(F) = C(CF(3))(3)) can be obtained. By addition of another equivalent of Me(3)Si–F–Al(OR(F))(3) to [f–al](–), gase...

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Detalles Bibliográficos
Autores principales: Martens, Arthur, Weis, Philippe, Krummer, Michael Christian, Kreuzer, Marvin, Meierhöfer, Andreas, Meier, Stefan C., Bohnenberger, Jan, Scherer, Harald, Riddlestone, Ian, Krossing, Ingo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6137444/
https://www.ncbi.nlm.nih.gov/pubmed/30310626
http://dx.doi.org/10.1039/c8sc02591f

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