Enantioselective fluorination of homoallylic alcohols enabled by the tuning of non-covalent interactions

The study of the enantioselective fluorination of homoallylic alcohols via chiral anion phase transfer (CAPT) catalysis using an in situ generated directing group is described. Multivariate correlation analysis, including designer π-interaction derived parameters, revealed key structural features af...

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Detalles Bibliográficos
Autores principales: Coelho, Jaime A. S., Matsumoto, Akira, Orlandi, Manuel, Hilton, Margaret J., Sigman, Matthew S., Toste, F. Dean
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6137454/
https://www.ncbi.nlm.nih.gov/pubmed/30310638
http://dx.doi.org/10.1039/c8sc02223b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6137454/
https://www.ncbi.nlm.nih.gov/pubmed/30310638
http://dx.doi.org/10.1039/c8sc02223b

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