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Concyclic CH-π arrays for single-axis rotations of a bowl in a tube

The hydrogen bond is undoubtedly one of the most important non-covalent interactions. Among the several types of the hydrogen bonds, the CH–π interaction is a relatively new notion that is being recognised in chemistry and biology. Although the CH–π hydrogen bond and conventional hydrogen bonds shar...

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Detalles Bibliográficos
Autores principales: Matsuno, Taisuke, Fujita, Masahiro, Fukunaga, Kengo, Sato, Sota, Isobe, Hiroyuki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6141547/
https://www.ncbi.nlm.nih.gov/pubmed/30224711
http://dx.doi.org/10.1038/s41467-018-06270-6
Descripción
Sumario:The hydrogen bond is undoubtedly one of the most important non-covalent interactions. Among the several types of the hydrogen bonds, the CH–π interaction is a relatively new notion that is being recognised in chemistry and biology. Although the CH–π hydrogen bond and conventional hydrogen bonds share common features such as directionality, this weak interaction has played a secondary role in molecular recognition. In this study, we have devised a host–guest complex that is assembled solely by the CH–π hydrogen bonds. Multivalent interactions of a bowl-shaped hydrocarbon with its peripheral hydrogen atoms are made possible via CH–π hydrogen bonds by adopting a tubular hydrocarbon as a host for their enthalpy-driven complexation. Concyclic arrays of weak hydrogen bonds further allow dynamic rotational motions of the guest in the host. Solid-state analysis with crystallographic and spectroscopic methods reveal a single-axis rotation of the bowl in the tube.