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A challenging redox neutral Cp*Co(III)-catalysed alkylation of acetanilides with 3-buten-2-one: synthesis and key insights into the mechanism through DFT calculations

Traditional, established palladium cross-coupling procedures are widely applied in complex molecule synthesis; however, there is a significant disadvantage in the requirement for pre-functionalised substrates (commonly halides/triflates). Direct C–H activation protocols provide the opportunity for a...

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Detalles Bibliográficos
Autores principales: Kenny, Andrew, Pisarello, Alba, Bird, Arron, Chirila, Paula G, Hamilton, Alex, Whiteoak, Christopher J
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6142744/
https://www.ncbi.nlm.nih.gov/pubmed/30254701
http://dx.doi.org/10.3762/bjoc.14.212