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Non-metal-templated approaches to bis(borane) derivatives of macrocyclic dibridgehead diphosphines via alkene metathesis
Two routes to the title compounds are evaluated. First, a ca. 0.01 M CH(2)Cl(2) solution of H(3)B·P((CH(2))(6)CH=CH(2))(3) (1·BH(3)) is treated with 5 mol % of Grubbs' first generation catalyst (0 °C to reflux), followed by H(2) (5 bar) and Wilkinson's catalyst (55 °C). Column chromatograp...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6142775/ https://www.ncbi.nlm.nih.gov/pubmed/30254700 http://dx.doi.org/10.3762/bjoc.14.211 |