Robust Sandwich‐Structured Nanofluidic Diodes Modulating Ionic Transport for an Enhanced Electrochromic Performance

Biomimetic solid‐state nanofluidic diodes have attracted extensive research interest due to the possible applications in various fields, such as biosensing, energy conversion, and nanofluidic circuits. However, contributions of exterior surface to the transmembrane ionic transport are often ignored, which can be a crucial factor for ion rectification behavior. Herein, a rational design of robust sandwich‐structured nanofluidic diode is shown by creating opposite charges on the exterior surfaces of a nanoporous membrane using inorganic oxides with distinct isoelectric points. Potential‐induced changes in ion concentration within the nanopores lead to a current rectification; the results are subsequently supported by a theoretical simulation. Except for providing surface charges, functional inorganic oxides used in this work are complementary electrochromic materials. Hence, the sandwich‐structured nanofluidic diode is further developed into an electrochromic membrane exhibiting a visual color change in response to redox potentials. The results show that the surface‐charge‐governed ionic transport and the nanoporous structure facilitate the migration of Li(+) ions, which in turn enhance the electrochromic performance. It is envisioned that this work will create new avenues to design and optimize nanofluidic diodes and electrochromic devices.