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Ag(+) doped into azo-linked conjugated microporous polymer for volatile iodine capture and detection of heavy metal ions

We herein report the construction of a novel azo-linked conjugated microporous polymers (Ag@Azo(TPE)-CMP), which possesses permanent porous structure and Ag(+) loading up of 7.62% in the skeleton as effective sorption sites. Ag@Azo(TPE)-CMP shows considerable adsorption capacity of iodine of 202 wt%...

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Detalles Bibliográficos
Autores principales: Liu, Minghan, Yao, Chan, Liu, Chunbo, Xu, Yanhong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6145922/
https://www.ncbi.nlm.nih.gov/pubmed/30232370
http://dx.doi.org/10.1038/s41598-018-32383-5
Descripción
Sumario:We herein report the construction of a novel azo-linked conjugated microporous polymers (Ag@Azo(TPE)-CMP), which possesses permanent porous structure and Ag(+) loading up of 7.62% in the skeleton as effective sorption sites. Ag@Azo(TPE)-CMP shows considerable adsorption capacity of iodine of 202 wt% in iodine vapor at 350 K. In addition, Ag@Azo(TPE)-CMP can effectively remove heavy ions from ethanol-water solution.