Microwave-Accelerated Iodination of Some Aromatic Amines, Using Urea-Hydrogen Peroxide Addition Compound (UHP) as the Oxidant†

A fast and simple method for the oxidative iodination of some aromatic amines, under microwave irradiation, is reported, using diiodine and the the strongly H-bonded urea-hydrogen peroxide addition compound (H(2)NCONH(2)···H(2)O(2), UHP) as the oxidant. The reactions were carried out in boiling CHCl...

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Autores principales: Sosnowski, Maciej, Skulski, Lech
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2002
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6146421/
http://dx.doi.org/10.3390/71200867
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author Sosnowski, Maciej
Skulski, Lech
author_facet Sosnowski, Maciej
Skulski, Lech
author_sort Sosnowski, Maciej
collection PubMed
description A fast and simple method for the oxidative iodination of some aromatic amines, under microwave irradiation, is reported, using diiodine and the the strongly H-bonded urea-hydrogen peroxide addition compound (H(2)NCONH(2)···H(2)O(2), UHP) as the oxidant. The reactions were carried out in boiling CHCl(3) under a reflux condenser to afford, within 10 minutes, the purified monoiodinated products in 40-80% yields.
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spelling pubmed-61464212018-11-19 Microwave-Accelerated Iodination of Some Aromatic Amines, Using Urea-Hydrogen Peroxide Addition Compound (UHP) as the Oxidant† Sosnowski, Maciej Skulski, Lech Molecules Article A fast and simple method for the oxidative iodination of some aromatic amines, under microwave irradiation, is reported, using diiodine and the the strongly H-bonded urea-hydrogen peroxide addition compound (H(2)NCONH(2)···H(2)O(2), UHP) as the oxidant. The reactions were carried out in boiling CHCl(3) under a reflux condenser to afford, within 10 minutes, the purified monoiodinated products in 40-80% yields. MDPI 2002-12-31 /pmc/articles/PMC6146421/ http://dx.doi.org/10.3390/71200867 Text en © 2002 by MDPI (http://www.mdpi.org). Reproduction is permitted for noncommercial purposes.
spellingShingle Article
Sosnowski, Maciej
Skulski, Lech
Microwave-Accelerated Iodination of Some Aromatic Amines, Using Urea-Hydrogen Peroxide Addition Compound (UHP) as the Oxidant†
title Microwave-Accelerated Iodination of Some Aromatic Amines, Using Urea-Hydrogen Peroxide Addition Compound (UHP) as the Oxidant†
title_full Microwave-Accelerated Iodination of Some Aromatic Amines, Using Urea-Hydrogen Peroxide Addition Compound (UHP) as the Oxidant†
title_fullStr Microwave-Accelerated Iodination of Some Aromatic Amines, Using Urea-Hydrogen Peroxide Addition Compound (UHP) as the Oxidant†
title_full_unstemmed Microwave-Accelerated Iodination of Some Aromatic Amines, Using Urea-Hydrogen Peroxide Addition Compound (UHP) as the Oxidant†
title_short Microwave-Accelerated Iodination of Some Aromatic Amines, Using Urea-Hydrogen Peroxide Addition Compound (UHP) as the Oxidant†
title_sort microwave-accelerated iodination of some aromatic amines, using urea-hydrogen peroxide addition compound (uhp) as the oxidant†
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6146421/
http://dx.doi.org/10.3390/71200867
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AT skulskilech microwaveacceleratediodinationofsomearomaticaminesusingureahydrogenperoxideadditioncompounduhpastheoxidant

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