Synthetic Studies on Diels-Alder Adducts: Intramolecular Interactions Between Two Functions

In this paper we describe the synthesis of a γ,δ-unsaturated aldehyde from a bicyclic Diels-Alder adduct, to be used in future electrocyclic reaction studies. A number of reactions produced undesired materials resulting from the interaction between functions, forcing the use of partial protection to...

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Detalles Bibliográficos
Autores principales: Constantino, Mauricio Gomes, de Souza, Altamiro Xavier, da Silva, Gil Valdo José
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2002
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6146423/
http://dx.doi.org/10.3390/70600475
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author Constantino, Mauricio Gomes
de Souza, Altamiro Xavier
da Silva, Gil Valdo José
author_facet Constantino, Mauricio Gomes
de Souza, Altamiro Xavier
da Silva, Gil Valdo José
author_sort Constantino, Mauricio Gomes
collection PubMed
description In this paper we describe the synthesis of a γ,δ-unsaturated aldehyde from a bicyclic Diels-Alder adduct, to be used in future electrocyclic reaction studies. A number of reactions produced undesired materials resulting from the interaction between functions, forcing the use of partial protection to accomplish a synthesis that would be otherwise straightforward. Suggestions to account for the results are given.
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spelling pubmed-61464232018-11-19 Synthetic Studies on Diels-Alder Adducts: Intramolecular Interactions Between Two Functions Constantino, Mauricio Gomes de Souza, Altamiro Xavier da Silva, Gil Valdo José Molecules Article In this paper we describe the synthesis of a γ,δ-unsaturated aldehyde from a bicyclic Diels-Alder adduct, to be used in future electrocyclic reaction studies. A number of reactions produced undesired materials resulting from the interaction between functions, forcing the use of partial protection to accomplish a synthesis that would be otherwise straightforward. Suggestions to account for the results are given. MDPI 2002-06-30 /pmc/articles/PMC6146423/ http://dx.doi.org/10.3390/70600475 Text en © 2002 by MDPI (http://www.mdpi.org). Reproduction is permitted for noncommercial purposes.
spellingShingle Article
Constantino, Mauricio Gomes
de Souza, Altamiro Xavier
da Silva, Gil Valdo José
Synthetic Studies on Diels-Alder Adducts: Intramolecular Interactions Between Two Functions
title Synthetic Studies on Diels-Alder Adducts: Intramolecular Interactions Between Two Functions
title_full Synthetic Studies on Diels-Alder Adducts: Intramolecular Interactions Between Two Functions
title_fullStr Synthetic Studies on Diels-Alder Adducts: Intramolecular Interactions Between Two Functions
title_full_unstemmed Synthetic Studies on Diels-Alder Adducts: Intramolecular Interactions Between Two Functions
title_short Synthetic Studies on Diels-Alder Adducts: Intramolecular Interactions Between Two Functions
title_sort synthetic studies on diels-alder adducts: intramolecular interactions between two functions
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6146423/
http://dx.doi.org/10.3390/70600475
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AT dasilvagilvaldojose syntheticstudiesondielsalderadductsintramolecularinteractionsbetweentwofunctions

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