Functionalization of Phenyl Rings by Imidoylnitrenes. 3 The Effects of Resonance, Steric, and Inductive Properties on the Reactivity or Selectivity of Nitrenes and the Stability of their Precursors

The thermal decomposition of imidoyl azides (ArO-C=N-Z)-N(3), (Ar = p-NO(2)-C(6)H(4)-, p-Br-C(6)H(4)-, p-Cl-C(6)H(4)-, p-C(6)H(5)-, p-CH(3)-C(6)H(4)-, 2,4-dimethyl-C(6)H(3)-, 2,4,6-trimethyl-C(6)H(2)-, p-CH(3)O-C(6)H(4)- and Z = p-CH(3)-C(6)H(4)-SO(2)-, 2,4,6-trimethyl-C(6)H(2)-SO(2)-, CN) in the so...

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Autores principales: Dabbagh, Hossein A., Karimzadeh, Reza
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2002
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6146427/
http://dx.doi.org/10.3390/70200189
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author Dabbagh, Hossein A.
Karimzadeh, Reza
author_facet Dabbagh, Hossein A.
Karimzadeh, Reza
author_sort Dabbagh, Hossein A.
collection PubMed
description The thermal decomposition of imidoyl azides (ArO-C=N-Z)-N(3), (Ar = p-NO(2)-C(6)H(4)-, p-Br-C(6)H(4)-, p-Cl-C(6)H(4)-, p-C(6)H(5)-, p-CH(3)-C(6)H(4)-, 2,4-dimethyl-C(6)H(3)-, 2,4,6-trimethyl-C(6)H(2)-, p-CH(3)O-C(6)H(4)- and Z = p-CH(3)-C(6)H(4)-SO(2)-, 2,4,6-trimethyl-C(6)H(2)-SO(2)-, CN) in the solid phase and in anisole has been studied in detail. The sensitivity of nitrenes and nitrene precursors (imidoyl azides) towards substitution changes in the aryloxy (ArO) and Z moieties is examined.
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spelling pubmed-61464272018-11-19 Functionalization of Phenyl Rings by Imidoylnitrenes. 3 The Effects of Resonance, Steric, and Inductive Properties on the Reactivity or Selectivity of Nitrenes and the Stability of their Precursors Dabbagh, Hossein A. Karimzadeh, Reza Molecules Article The thermal decomposition of imidoyl azides (ArO-C=N-Z)-N(3), (Ar = p-NO(2)-C(6)H(4)-, p-Br-C(6)H(4)-, p-Cl-C(6)H(4)-, p-C(6)H(5)-, p-CH(3)-C(6)H(4)-, 2,4-dimethyl-C(6)H(3)-, 2,4,6-trimethyl-C(6)H(2)-, p-CH(3)O-C(6)H(4)- and Z = p-CH(3)-C(6)H(4)-SO(2)-, 2,4,6-trimethyl-C(6)H(2)-SO(2)-, CN) in the solid phase and in anisole has been studied in detail. The sensitivity of nitrenes and nitrene precursors (imidoyl azides) towards substitution changes in the aryloxy (ArO) and Z moieties is examined. MDPI 2002-02-28 /pmc/articles/PMC6146427/ http://dx.doi.org/10.3390/70200189 Text en © 2002 by MDPI (http://www.mdpi.org). Reproduction is permitted for non commercial purposes.
spellingShingle Article
Dabbagh, Hossein A.
Karimzadeh, Reza
Functionalization of Phenyl Rings by Imidoylnitrenes. 3 The Effects of Resonance, Steric, and Inductive Properties on the Reactivity or Selectivity of Nitrenes and the Stability of their Precursors
title Functionalization of Phenyl Rings by Imidoylnitrenes. 3 The Effects of Resonance, Steric, and Inductive Properties on the Reactivity or Selectivity of Nitrenes and the Stability of their Precursors
title_full Functionalization of Phenyl Rings by Imidoylnitrenes. 3 The Effects of Resonance, Steric, and Inductive Properties on the Reactivity or Selectivity of Nitrenes and the Stability of their Precursors
title_fullStr Functionalization of Phenyl Rings by Imidoylnitrenes. 3 The Effects of Resonance, Steric, and Inductive Properties on the Reactivity or Selectivity of Nitrenes and the Stability of their Precursors
title_full_unstemmed Functionalization of Phenyl Rings by Imidoylnitrenes. 3 The Effects of Resonance, Steric, and Inductive Properties on the Reactivity or Selectivity of Nitrenes and the Stability of their Precursors
title_short Functionalization of Phenyl Rings by Imidoylnitrenes. 3 The Effects of Resonance, Steric, and Inductive Properties on the Reactivity or Selectivity of Nitrenes and the Stability of their Precursors
title_sort functionalization of phenyl rings by imidoylnitrenes. 3 the effects of resonance, steric, and inductive properties on the reactivity or selectivity of nitrenes and the stability of their precursors
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6146427/
http://dx.doi.org/10.3390/70200189
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