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Synthesis of Thieno[2,3-d]-1,3-dithiol-2-thiones from Thieno[2,3-d]-1,2,3-thiadiazoles: Matryoshka-type autoclave for high-temperature, high-pressure thermolysis microscale reactions†
Thieno[2,3-d]-1,2,3-thiadiazoles (1) react with carbon disulfide in a "Matryoshka-type" double compartment autoclave [1] to yield thieno[2,3-d]-1,3-dithiol-2-thiones (2). With BH(3)/Me(2)S the cyclic trithiocarbonate (2d) is cleaved and the product characterized after methylation as 4b. Co...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2002
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6146433/ http://dx.doi.org/10.3390/70200145 |
| _version_ | 1783356392103477248 |
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| author | Jordis, Ulrich Bhattacharya, Kaberi Boamah, Philip Y. Lee, Ving J. |
| author_facet | Jordis, Ulrich Bhattacharya, Kaberi Boamah, Philip Y. Lee, Ving J. |
| author_sort | Jordis, Ulrich |
| collection | PubMed |
| description | Thieno[2,3-d]-1,2,3-thiadiazoles (1) react with carbon disulfide in a "Matryoshka-type" double compartment autoclave [1] to yield thieno[2,3-d]-1,3-dithiol-2-thiones (2). With BH(3)/Me(2)S the cyclic trithiocarbonate (2d) is cleaved and the product characterized after methylation as 4b. Compounds 7a and 7b are prepared via the thieno[2,3-d]-1,3-dithiolium salts (6) followed by NaBH(4)-reduction. |
| format | Online Article Text |
| id | pubmed-6146433 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2002 |
| publisher | MDPI |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-61464332018-11-19 Synthesis of Thieno[2,3-d]-1,3-dithiol-2-thiones from Thieno[2,3-d]-1,2,3-thiadiazoles: Matryoshka-type autoclave for high-temperature, high-pressure thermolysis microscale reactions† Jordis, Ulrich Bhattacharya, Kaberi Boamah, Philip Y. Lee, Ving J. Molecules Article Thieno[2,3-d]-1,2,3-thiadiazoles (1) react with carbon disulfide in a "Matryoshka-type" double compartment autoclave [1] to yield thieno[2,3-d]-1,3-dithiol-2-thiones (2). With BH(3)/Me(2)S the cyclic trithiocarbonate (2d) is cleaved and the product characterized after methylation as 4b. Compounds 7a and 7b are prepared via the thieno[2,3-d]-1,3-dithiolium salts (6) followed by NaBH(4)-reduction. MDPI 2002-02-28 /pmc/articles/PMC6146433/ http://dx.doi.org/10.3390/70200145 Text en © 2002 by MDPI (http://www.mdpi.org). Reproduction is permitted for non commercial purposes. |
| spellingShingle | Article Jordis, Ulrich Bhattacharya, Kaberi Boamah, Philip Y. Lee, Ving J. Synthesis of Thieno[2,3-d]-1,3-dithiol-2-thiones from Thieno[2,3-d]-1,2,3-thiadiazoles: Matryoshka-type autoclave for high-temperature, high-pressure thermolysis microscale reactions† |
| title | Synthesis of Thieno[2,3-d]-1,3-dithiol-2-thiones from Thieno[2,3-d]-1,2,3-thiadiazoles: Matryoshka-type autoclave for high-temperature, high-pressure thermolysis microscale reactions† |
| title_full | Synthesis of Thieno[2,3-d]-1,3-dithiol-2-thiones from Thieno[2,3-d]-1,2,3-thiadiazoles: Matryoshka-type autoclave for high-temperature, high-pressure thermolysis microscale reactions† |
| title_fullStr | Synthesis of Thieno[2,3-d]-1,3-dithiol-2-thiones from Thieno[2,3-d]-1,2,3-thiadiazoles: Matryoshka-type autoclave for high-temperature, high-pressure thermolysis microscale reactions† |
| title_full_unstemmed | Synthesis of Thieno[2,3-d]-1,3-dithiol-2-thiones from Thieno[2,3-d]-1,2,3-thiadiazoles: Matryoshka-type autoclave for high-temperature, high-pressure thermolysis microscale reactions† |
| title_short | Synthesis of Thieno[2,3-d]-1,3-dithiol-2-thiones from Thieno[2,3-d]-1,2,3-thiadiazoles: Matryoshka-type autoclave for high-temperature, high-pressure thermolysis microscale reactions† |
| title_sort | synthesis of thieno[2,3-d]-1,3-dithiol-2-thiones from thieno[2,3-d]-1,2,3-thiadiazoles: matryoshka-type autoclave for high-temperature, high-pressure thermolysis microscale reactions† |
| topic | Article |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6146433/ http://dx.doi.org/10.3390/70200145 |
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