Synthesis and Structure of the Cadmium (II) Complex: [Cd(C(5)H(5)N)(2)(S(2)CO-n-C(4)H(9))(2)]

The [Cd(C(5)H(5)N)(2)(S(2)CO-n-C(4)H(9))(2)] adduct of pyridine with [Cd(S(2)CO-n-C(4)H(9))(2)](n) was synthesized and characterized by IR, elemental analysis, (1)H-NMR and X-ray diffraction analysis. The crystasl belong to the monoclinic system, space group P2(1)/c with Z=2. Cell dimensions are a=1...

Descripción completa

Detalles Bibliográficos
Autores principales: Jiang, Xu Hong, Zhang, Wei Guang, Zhong, Yun, Wang, Sue Lein
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2002
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6146460/
http://dx.doi.org/10.3390/70700549
Descripción
Sumario:The [Cd(C(5)H(5)N)(2)(S(2)CO-n-C(4)H(9))(2)] adduct of pyridine with [Cd(S(2)CO-n-C(4)H(9))(2)](n) was synthesized and characterized by IR, elemental analysis, (1)H-NMR and X-ray diffraction analysis. The crystasl belong to the monoclinic system, space group P2(1)/c with Z=2. Cell dimensions are a=1.1094(12), b=0.6152(6), c=1.7985(19) nm, • =96.148(2)°, V=1.2204(2)nm(3). The tructure was refined to R=0.0246 and wR=0.0645 for 2624 reflections with I>2•(I). The complex has a centrosymmetric molecule structure.

Ejemplares similares