Total Synthesis of (-)-(7S,10R)-Calamenene and (-)-(7S,10R)- 2-Hydroxycalamenene by Use of a Ring-Closing Metathesis Reaction. A Comparison of the cis- and trans-Isomers

The title compounds have been synthesized starting from l-menthone by application of a ring-closing metathesis reaction to confirm their reported absolute and relative stereochemistry. Comparisons of the NMR spectra and specific rotations are also discussed.

Detalles Bibliográficos
Autores principales: Nakashima, Katsuyuki, Imoto, Masashi, Sono, Masakazu, Tori, Motoo, Nagashima, Fumihiro, Asakawa, Yoshinori
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2002
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6146462/
http://dx.doi.org/10.3390/70700517

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6146462/
http://dx.doi.org/10.3390/70700517

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