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The Behaviour of 1,2,3-Indantrione Towards Wittig-Horner Reagents
Wittig-Horner reagents 1a,b react with 1,2,3-indantrione (2) to give the dimeric adducts 3a and 3b, respectively. Moreover, 2 reacts with tert-butyl diethyl-phosphonoacetate (1c) yielding the ethylenic compound 4. On the other hand, 2 reacts with 1d to yield the phosphonate adduct 5. Mechanisms acco...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2002
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6146465/ http://dx.doi.org/10.3390/70100081 |
| _version_ | 1783356399593455616 |
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| author | Abd El-Rahman, N.M. Boulos, L.S. |
| author_facet | Abd El-Rahman, N.M. Boulos, L.S. |
| author_sort | Abd El-Rahman, N.M. |
| collection | PubMed |
| description | Wittig-Horner reagents 1a,b react with 1,2,3-indantrione (2) to give the dimeric adducts 3a and 3b, respectively. Moreover, 2 reacts with tert-butyl diethyl-phosphonoacetate (1c) yielding the ethylenic compound 4. On the other hand, 2 reacts with 1d to yield the phosphonate adduct 5. Mechanisms accounting for the formation of the new products are discussed and the probable structures of the products are presented based on compatible analytical and spectral data. |
| format | Online Article Text |
| id | pubmed-6146465 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2002 |
| publisher | MDPI |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-61464652018-11-19 The Behaviour of 1,2,3-Indantrione Towards Wittig-Horner Reagents Abd El-Rahman, N.M. Boulos, L.S. Molecules Article Wittig-Horner reagents 1a,b react with 1,2,3-indantrione (2) to give the dimeric adducts 3a and 3b, respectively. Moreover, 2 reacts with tert-butyl diethyl-phosphonoacetate (1c) yielding the ethylenic compound 4. On the other hand, 2 reacts with 1d to yield the phosphonate adduct 5. Mechanisms accounting for the formation of the new products are discussed and the probable structures of the products are presented based on compatible analytical and spectral data. MDPI 2002-01-30 /pmc/articles/PMC6146465/ http://dx.doi.org/10.3390/70100081 Text en © 2002 by MDPI (http://www.mdpi.org). Reproduction is permitted for noncommercial purposes. |
| spellingShingle | Article Abd El-Rahman, N.M. Boulos, L.S. The Behaviour of 1,2,3-Indantrione Towards Wittig-Horner Reagents |
| title | The Behaviour of 1,2,3-Indantrione Towards Wittig-Horner Reagents |
| title_full | The Behaviour of 1,2,3-Indantrione Towards Wittig-Horner Reagents |
| title_fullStr | The Behaviour of 1,2,3-Indantrione Towards Wittig-Horner Reagents |
| title_full_unstemmed | The Behaviour of 1,2,3-Indantrione Towards Wittig-Horner Reagents |
| title_short | The Behaviour of 1,2,3-Indantrione Towards Wittig-Horner Reagents |
| title_sort | behaviour of 1,2,3-indantrione towards wittig-horner reagents |
| topic | Article |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6146465/ http://dx.doi.org/10.3390/70100081 |
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