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ElectronTransfer Induced Ring Opening of α-Epoxyketones: Spirodioxolane Formation

Stereospecific formation of spirodioxolanes has been observed on electron transfer induced ring opening of α-epoxyketones by 2,4,6-triphenylpyrylium tetrafluoroborate in the presence of cyclohexanone.

Detalles Bibliográficos
Autores principales: Memarian, Hamid R., Nikpour, Farzad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2002
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6146470/
http://dx.doi.org/10.3390/70100063
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author Memarian, Hamid R.
Nikpour, Farzad
author_facet Memarian, Hamid R.
Nikpour, Farzad
author_sort Memarian, Hamid R.
collection PubMed
description Stereospecific formation of spirodioxolanes has been observed on electron transfer induced ring opening of α-epoxyketones by 2,4,6-triphenylpyrylium tetrafluoroborate in the presence of cyclohexanone.
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spelling pubmed-61464702018-11-19 ElectronTransfer Induced Ring Opening of α-Epoxyketones: Spirodioxolane Formation Memarian, Hamid R. Nikpour, Farzad Molecules Article Stereospecific formation of spirodioxolanes has been observed on electron transfer induced ring opening of α-epoxyketones by 2,4,6-triphenylpyrylium tetrafluoroborate in the presence of cyclohexanone. MDPI 2002-01-31 /pmc/articles/PMC6146470/ http://dx.doi.org/10.3390/70100063 Text en © 2002 by MDPI (http://www.mdpi.org). Reproduction is permitted for noncommercial purposes.
spellingShingle Article
Memarian, Hamid R.
Nikpour, Farzad
ElectronTransfer Induced Ring Opening of α-Epoxyketones: Spirodioxolane Formation
title ElectronTransfer Induced Ring Opening of α-Epoxyketones: Spirodioxolane Formation
title_full ElectronTransfer Induced Ring Opening of α-Epoxyketones: Spirodioxolane Formation
title_fullStr ElectronTransfer Induced Ring Opening of α-Epoxyketones: Spirodioxolane Formation
title_full_unstemmed ElectronTransfer Induced Ring Opening of α-Epoxyketones: Spirodioxolane Formation
title_short ElectronTransfer Induced Ring Opening of α-Epoxyketones: Spirodioxolane Formation
title_sort electrontransfer induced ring opening of α-epoxyketones: spirodioxolane formation
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6146470/
http://dx.doi.org/10.3390/70100063
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AT nikpourfarzad electrontransferinducedringopeningofaepoxyketonesspirodioxolaneformation