Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates†

The trichloromethylsulfonyl-, dichloromethylsulfonyl-, chlorosulfonyl-, and fluorosulfonyl esters of a neopentyl-type alcohol have been prepared via sulfonylation or sulfinylation followed by oxidation. The preparative usefulness and potential of the transformations are discussed.

Detalles Bibliográficos
Autores principales: Netscher, Thomas, Bohrer, Patrick
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2002
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6146488/
http://dx.doi.org/10.3390/70800601
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author Netscher, Thomas
Bohrer, Patrick
author_facet Netscher, Thomas
Bohrer, Patrick
author_sort Netscher, Thomas
collection PubMed
description The trichloromethylsulfonyl-, dichloromethylsulfonyl-, chlorosulfonyl-, and fluorosulfonyl esters of a neopentyl-type alcohol have been prepared via sulfonylation or sulfinylation followed by oxidation. The preparative usefulness and potential of the transformations are discussed.
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spelling pubmed-61464882018-11-19 Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates† Netscher, Thomas Bohrer, Patrick Molecules Article The trichloromethylsulfonyl-, dichloromethylsulfonyl-, chlorosulfonyl-, and fluorosulfonyl esters of a neopentyl-type alcohol have been prepared via sulfonylation or sulfinylation followed by oxidation. The preparative usefulness and potential of the transformations are discussed. MDPI 2002-08-31 /pmc/articles/PMC6146488/ http://dx.doi.org/10.3390/70800601 Text en © 2002 by MDPI (http://www.mdpi.org). Reproduction is permitted for noncommercial purposes.
spellingShingle Article
Netscher, Thomas
Bohrer, Patrick
Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates†
title Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates†
title_full Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates†
title_fullStr Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates†
title_full_unstemmed Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates†
title_short Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates†
title_sort towards highly activating leaving groups: studies on the preparation of some halogenated alkyl sulfonates†
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6146488/
http://dx.doi.org/10.3390/70800601
work_keys_str_mv AT netscherthomas towardshighlyactivatingleavinggroupsstudiesonthepreparationofsomehalogenatedalkylsulfonates
AT bohrerpatrick towardshighlyactivatingleavinggroupsstudiesonthepreparationofsomehalogenatedalkylsulfonates

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