Easy Preparation of [Bis(trifluoroacetoxy)iodo]arenes from Iodoarenes, with Sodium Percarbonate as the Oxidant†

Easy and effective preparations of the nearly pure [bis(trifluoroacetoxy)-iodo]arenes, ArI(OCOCF)(3), from some iodoarenes, ArI, are reported, using an anhydrous sodium percarbonate/(CF(3)CO)(2)O/CH(2)Cl(2) system. The colorless, freshly prepared ArI(OCOCF(3))(2) thus obtained were 98-99% pure (by i...

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Detalles Bibliográficos
Autores principales: Kazmierczak, Pawel, Skulski, Lech
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2002
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6146490/
http://dx.doi.org/10.3390/71100810
Descripción
Sumario:Easy and effective preparations of the nearly pure [bis(trifluoroacetoxy)-iodo]arenes, ArI(OCOCF)(3), from some iodoarenes, ArI, are reported, using an anhydrous sodium percarbonate/(CF(3)CO)(2)O/CH(2)Cl(2) system. The colorless, freshly prepared ArI(OCOCF(3))(2) thus obtained were 98-99% pure (by iodometry).

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