Easy Preparation of [Bis(trifluoroacetoxy)iodo]arenes from Iodoarenes, with Sodium Percarbonate as the Oxidant†

Easy and effective preparations of the nearly pure [bis(trifluoroacetoxy)-iodo]arenes, ArI(OCOCF)(3), from some iodoarenes, ArI, are reported, using an anhydrous sodium percarbonate/(CF(3)CO)(2)O/CH(2)Cl(2) system. The colorless, freshly prepared ArI(OCOCF(3))(2) thus obtained were 98-99% pure (by i...

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Autores principales: Kazmierczak, Pawel, Skulski, Lech
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2002
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6146490/
http://dx.doi.org/10.3390/71100810
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author Kazmierczak, Pawel
Skulski, Lech
author_facet Kazmierczak, Pawel
Skulski, Lech
author_sort Kazmierczak, Pawel
collection PubMed
description Easy and effective preparations of the nearly pure [bis(trifluoroacetoxy)-iodo]arenes, ArI(OCOCF)(3), from some iodoarenes, ArI, are reported, using an anhydrous sodium percarbonate/(CF(3)CO)(2)O/CH(2)Cl(2) system. The colorless, freshly prepared ArI(OCOCF(3))(2) thus obtained were 98-99% pure (by iodometry).
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spelling pubmed-61464902018-11-19 Easy Preparation of [Bis(trifluoroacetoxy)iodo]arenes from Iodoarenes, with Sodium Percarbonate as the Oxidant† Kazmierczak, Pawel Skulski, Lech Molecules Article Easy and effective preparations of the nearly pure [bis(trifluoroacetoxy)-iodo]arenes, ArI(OCOCF)(3), from some iodoarenes, ArI, are reported, using an anhydrous sodium percarbonate/(CF(3)CO)(2)O/CH(2)Cl(2) system. The colorless, freshly prepared ArI(OCOCF(3))(2) thus obtained were 98-99% pure (by iodometry). MDPI 2002-11-30 /pmc/articles/PMC6146490/ http://dx.doi.org/10.3390/71100810 Text en © 2002 by MDPI (http://www.mdpi.org). Reproduction is permitted for noncommercial purposes.
spellingShingle Article
Kazmierczak, Pawel
Skulski, Lech
Easy Preparation of [Bis(trifluoroacetoxy)iodo]arenes from Iodoarenes, with Sodium Percarbonate as the Oxidant†
title Easy Preparation of [Bis(trifluoroacetoxy)iodo]arenes from Iodoarenes, with Sodium Percarbonate as the Oxidant†
title_full Easy Preparation of [Bis(trifluoroacetoxy)iodo]arenes from Iodoarenes, with Sodium Percarbonate as the Oxidant†
title_fullStr Easy Preparation of [Bis(trifluoroacetoxy)iodo]arenes from Iodoarenes, with Sodium Percarbonate as the Oxidant†
title_full_unstemmed Easy Preparation of [Bis(trifluoroacetoxy)iodo]arenes from Iodoarenes, with Sodium Percarbonate as the Oxidant†
title_short Easy Preparation of [Bis(trifluoroacetoxy)iodo]arenes from Iodoarenes, with Sodium Percarbonate as the Oxidant†
title_sort easy preparation of [bis(trifluoroacetoxy)iodo]arenes from iodoarenes, with sodium percarbonate as the oxidant†
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6146490/
http://dx.doi.org/10.3390/71100810
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AT skulskilech easypreparationofbistrifluoroacetoxyiodoarenesfromiodoareneswithsodiumpercarbonateastheoxidant

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