Synthesis, Crystal Structure, and Conformation of Methyl 5-O-acetyl-5-cyano-6-deoxy-2,3-O-isopropylidene-β-l-gulofuranoside

Methyl 5-O-acetyl-5-cyano-6-deoxy-2,3-O-isopropylidene-β-l-gulofuranoside was prepared in high yield from methyl 6-deoxy-2,3-O-isopropylidene-α-d-lyxo-pentodialdo-1,4-furanoside. The configuration at the C5 atom was unambiguosly established by single crystal X-ray analysis of the corresponding 5-O-a...

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Autores principales: Mičová, Júlia, Steiner, Bohumil, Koóš, Miroslav, Gajdoš, Ján, Langer, Vratislav, Gyepesová, Dalma
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2002
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6146502/
http://dx.doi.org/10.3390/70500437
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author Mičová, Júlia
Steiner, Bohumil
Koóš, Miroslav
Gajdoš, Ján
Langer, Vratislav
Gyepesová, Dalma
author_facet Mičová, Júlia
Steiner, Bohumil
Koóš, Miroslav
Gajdoš, Ján
Langer, Vratislav
Gyepesová, Dalma
author_sort Mičová, Júlia
collection PubMed
description Methyl 5-O-acetyl-5-cyano-6-deoxy-2,3-O-isopropylidene-β-l-gulofuranoside was prepared in high yield from methyl 6-deoxy-2,3-O-isopropylidene-α-d-lyxo-pentodialdo-1,4-furanoside. The configuration at the C5 atom was unambiguosly established by single crystal X-ray analysis of the corresponding 5-O-acetyl derivative. The conformation of the furanose and 1,3-dioxolane rings is also discussed.
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spelling pubmed-61465022018-11-19 Synthesis, Crystal Structure, and Conformation of Methyl 5-O-acetyl-5-cyano-6-deoxy-2,3-O-isopropylidene-β-l-gulofuranoside Mičová, Júlia Steiner, Bohumil Koóš, Miroslav Gajdoš, Ján Langer, Vratislav Gyepesová, Dalma Molecules Article Methyl 5-O-acetyl-5-cyano-6-deoxy-2,3-O-isopropylidene-β-l-gulofuranoside was prepared in high yield from methyl 6-deoxy-2,3-O-isopropylidene-α-d-lyxo-pentodialdo-1,4-furanoside. The configuration at the C5 atom was unambiguosly established by single crystal X-ray analysis of the corresponding 5-O-acetyl derivative. The conformation of the furanose and 1,3-dioxolane rings is also discussed. MDPI 2002-05-31 /pmc/articles/PMC6146502/ http://dx.doi.org/10.3390/70500437 Text en © 2002 by MDPI (http://www.mdpi.org). Reproduction is permitted for noncommercial purposes.
spellingShingle Article
Mičová, Júlia
Steiner, Bohumil
Koóš, Miroslav
Gajdoš, Ján
Langer, Vratislav
Gyepesová, Dalma
Synthesis, Crystal Structure, and Conformation of Methyl 5-O-acetyl-5-cyano-6-deoxy-2,3-O-isopropylidene-β-l-gulofuranoside
title Synthesis, Crystal Structure, and Conformation of Methyl 5-O-acetyl-5-cyano-6-deoxy-2,3-O-isopropylidene-β-l-gulofuranoside
title_full Synthesis, Crystal Structure, and Conformation of Methyl 5-O-acetyl-5-cyano-6-deoxy-2,3-O-isopropylidene-β-l-gulofuranoside
title_fullStr Synthesis, Crystal Structure, and Conformation of Methyl 5-O-acetyl-5-cyano-6-deoxy-2,3-O-isopropylidene-β-l-gulofuranoside
title_full_unstemmed Synthesis, Crystal Structure, and Conformation of Methyl 5-O-acetyl-5-cyano-6-deoxy-2,3-O-isopropylidene-β-l-gulofuranoside
title_short Synthesis, Crystal Structure, and Conformation of Methyl 5-O-acetyl-5-cyano-6-deoxy-2,3-O-isopropylidene-β-l-gulofuranoside
title_sort synthesis, crystal structure, and conformation of methyl 5-o-acetyl-5-cyano-6-deoxy-2,3-o-isopropylidene-β-l-gulofuranoside
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6146502/
http://dx.doi.org/10.3390/70500437
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