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Synthesis and Rearrangement of 3-Methyl-1,4-pentadiyne-3-ol†
An efficient synthesis and rearrangement of 3-methyl-1,4-pentadiyne-3-ol (1) using perrhenate- and Mo(VI)-catalysts is reported. The by-products 3,6-dimethyl-1,4,7-octatriyne-3,6-diol (2) and 3-ethynyl-5-methyl-1,6-heptadiyne-3,5-diol (3) were isolated and spectroscopically characterized. A possible...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2002
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6146540/ http://dx.doi.org/10.3390/70300341 |
| _version_ | 1783356415135449088 |
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| author | Buser, Dominik Pauling, Horst Thum, Andreas Bonrath, Werner |
| author_facet | Buser, Dominik Pauling, Horst Thum, Andreas Bonrath, Werner |
| author_sort | Buser, Dominik |
| collection | PubMed |
| description | An efficient synthesis and rearrangement of 3-methyl-1,4-pentadiyne-3-ol (1) using perrhenate- and Mo(VI)-catalysts is reported. The by-products 3,6-dimethyl-1,4,7-octatriyne-3,6-diol (2) and 3-ethynyl-5-methyl-1,6-heptadiyne-3,5-diol (3) were isolated and spectroscopically characterized. A possible reaction mechanism for the formation of the by-products is discussed. |
| format | Online Article Text |
| id | pubmed-6146540 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2002 |
| publisher | MDPI |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-61465402018-11-19 Synthesis and Rearrangement of 3-Methyl-1,4-pentadiyne-3-ol† Buser, Dominik Pauling, Horst Thum, Andreas Bonrath, Werner Molecules Article An efficient synthesis and rearrangement of 3-methyl-1,4-pentadiyne-3-ol (1) using perrhenate- and Mo(VI)-catalysts is reported. The by-products 3,6-dimethyl-1,4,7-octatriyne-3,6-diol (2) and 3-ethynyl-5-methyl-1,6-heptadiyne-3,5-diol (3) were isolated and spectroscopically characterized. A possible reaction mechanism for the formation of the by-products is discussed. MDPI 2002-03-31 /pmc/articles/PMC6146540/ http://dx.doi.org/10.3390/70300341 Text en © 2002 by MDPI (http://www.mdpi.org). Reproduction is permitted for non commercial purposes. |
| spellingShingle | Article Buser, Dominik Pauling, Horst Thum, Andreas Bonrath, Werner Synthesis and Rearrangement of 3-Methyl-1,4-pentadiyne-3-ol† |
| title | Synthesis and Rearrangement of 3-Methyl-1,4-pentadiyne-3-ol† |
| title_full | Synthesis and Rearrangement of 3-Methyl-1,4-pentadiyne-3-ol† |
| title_fullStr | Synthesis and Rearrangement of 3-Methyl-1,4-pentadiyne-3-ol† |
| title_full_unstemmed | Synthesis and Rearrangement of 3-Methyl-1,4-pentadiyne-3-ol† |
| title_short | Synthesis and Rearrangement of 3-Methyl-1,4-pentadiyne-3-ol† |
| title_sort | synthesis and rearrangement of 3-methyl-1,4-pentadiyne-3-ol† |
| topic | Article |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6146540/ http://dx.doi.org/10.3390/70300341 |
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