First Example of Direct Transformation of Alkylbenzenes to 1,3-Benzodioxoles by Oxidation with o-Chloranil

The reaction of alkyl-substituted benzenes with o-chloranil at an elevated temperature was found to give 4,5,6,7-tetrachloro-1,3-benzodioxoles via benzylic oxidation and subsequent acetal formation, albeit in poor yields.

Detalles Bibliográficos
Autores principales: Rahman, Sheikh Maksudur, Kobayashi, Tomoshige
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2002
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6146779/
http://dx.doi.org/10.3390/71100840
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author Rahman, Sheikh Maksudur
Kobayashi, Tomoshige
author_facet Rahman, Sheikh Maksudur
Kobayashi, Tomoshige
author_sort Rahman, Sheikh Maksudur
collection PubMed
description The reaction of alkyl-substituted benzenes with o-chloranil at an elevated temperature was found to give 4,5,6,7-tetrachloro-1,3-benzodioxoles via benzylic oxidation and subsequent acetal formation, albeit in poor yields.
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spelling pubmed-61467792018-11-19 First Example of Direct Transformation of Alkylbenzenes to 1,3-Benzodioxoles by Oxidation with o-Chloranil Rahman, Sheikh Maksudur Kobayashi, Tomoshige Molecules Article The reaction of alkyl-substituted benzenes with o-chloranil at an elevated temperature was found to give 4,5,6,7-tetrachloro-1,3-benzodioxoles via benzylic oxidation and subsequent acetal formation, albeit in poor yields. MDPI 2002-11-30 /pmc/articles/PMC6146779/ http://dx.doi.org/10.3390/71100840 Text en © 2002 by MDPI (http://www.mdpi.org). Reproduction is permitted for noncommercial purposes.
spellingShingle Article
Rahman, Sheikh Maksudur
Kobayashi, Tomoshige
First Example of Direct Transformation of Alkylbenzenes to 1,3-Benzodioxoles by Oxidation with o-Chloranil
title First Example of Direct Transformation of Alkylbenzenes to 1,3-Benzodioxoles by Oxidation with o-Chloranil
title_full First Example of Direct Transformation of Alkylbenzenes to 1,3-Benzodioxoles by Oxidation with o-Chloranil
title_fullStr First Example of Direct Transformation of Alkylbenzenes to 1,3-Benzodioxoles by Oxidation with o-Chloranil
title_full_unstemmed First Example of Direct Transformation of Alkylbenzenes to 1,3-Benzodioxoles by Oxidation with o-Chloranil
title_short First Example of Direct Transformation of Alkylbenzenes to 1,3-Benzodioxoles by Oxidation with o-Chloranil
title_sort first example of direct transformation of alkylbenzenes to 1,3-benzodioxoles by oxidation with o-chloranil
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6146779/
http://dx.doi.org/10.3390/71100840
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AT kobayashitomoshige firstexampleofdirecttransformationofalkylbenzenesto13benzodioxolesbyoxidationwithochloranil

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