A Method for Synthesizing Partially Substituted Cucurbit[n]uril

A novel approach to cucurbituril synthesis is described where partial substitution is introduced into cucurbit[n]uril. The identification of homologues (and their substitution) in reaction mixtures is achieved by a combination of ESMS and the use of the molecular probes (guests) 1,4-dioxane and 1,9-...

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Detalles Bibliográficos
Autores principales: Day, Anthony I., Arnold, Alan P., Blanch, Rodney J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2003
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6146886/
http://dx.doi.org/10.3390/80100074
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author Day, Anthony I.
Arnold, Alan P.
Blanch, Rodney J.
author_facet Day, Anthony I.
Arnold, Alan P.
Blanch, Rodney J.
author_sort Day, Anthony I.
collection PubMed
description A novel approach to cucurbituril synthesis is described where partial substitution is introduced into cucurbit[n]uril. The identification of homologues (and their substitution) in reaction mixtures is achieved by a combination of ESMS and the use of the molecular probes (guests) 1,4-dioxane and 1,9-octanediamine. A unique symmetrical hexamethylcucurbit[3,3]uril, the major product, was isolated and characterized.
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spelling pubmed-61468862018-11-19 A Method for Synthesizing Partially Substituted Cucurbit[n]uril Day, Anthony I. Arnold, Alan P. Blanch, Rodney J. Molecules Article A novel approach to cucurbituril synthesis is described where partial substitution is introduced into cucurbit[n]uril. The identification of homologues (and their substitution) in reaction mixtures is achieved by a combination of ESMS and the use of the molecular probes (guests) 1,4-dioxane and 1,9-octanediamine. A unique symmetrical hexamethylcucurbit[3,3]uril, the major product, was isolated and characterized. MDPI 2003-01-31 /pmc/articles/PMC6146886/ http://dx.doi.org/10.3390/80100074 Text en © 2003 by MDPI (http://www.mdpi.org). Reproduction is permitted for noncommercial purposes.
spellingShingle Article
Day, Anthony I.
Arnold, Alan P.
Blanch, Rodney J.
A Method for Synthesizing Partially Substituted Cucurbit[n]uril
title A Method for Synthesizing Partially Substituted Cucurbit[n]uril
title_full A Method for Synthesizing Partially Substituted Cucurbit[n]uril
title_fullStr A Method for Synthesizing Partially Substituted Cucurbit[n]uril
title_full_unstemmed A Method for Synthesizing Partially Substituted Cucurbit[n]uril
title_short A Method for Synthesizing Partially Substituted Cucurbit[n]uril
title_sort method for synthesizing partially substituted cucurbit[n]uril
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6146886/
http://dx.doi.org/10.3390/80100074
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