Preparation Crystal Structure of (1S, 5S, 7S, 8R)-8-Hydroxy-7-phenyl-2,6-dioxabicyclo[3.3.0]octan-3-one

The absolute configuration at two newly formed stereogenic centres (5S, 7S) during the key steps of the total synthesis of naturally occuring goniothalesdiol was established by single-crystal X-ray diffraction analysis relative to stereocentres (1S, 8R) of the title compound (alternatively named 3,6...

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Autores principales: Langer, Vratislav, Gyepesová, Dalma, Koman, Marian, Kapitán, Peter, Babjak, Matej, Gracza, Tibor, Koóš, Miroslav
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2003
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Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6147014/
http://dx.doi.org/10.3390/80700599
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author Langer, Vratislav
Gyepesová, Dalma
Koman, Marian
Kapitán, Peter
Babjak, Matej
Gracza, Tibor
Koóš, Miroslav
author_facet Langer, Vratislav
Gyepesová, Dalma
Koman, Marian
Kapitán, Peter
Babjak, Matej
Gracza, Tibor
Koóš, Miroslav
author_sort Langer, Vratislav
collection PubMed
description The absolute configuration at two newly formed stereogenic centres (5S, 7S) during the key steps of the total synthesis of naturally occuring goniothalesdiol was established by single-crystal X-ray diffraction analysis relative to stereocentres (1S, 8R) of the title compound (alternatively named 3,6-anhydro-2-deoxy-6-phenyl-l-ido-1,4-hexonolactone, C(12)H(12)O(4)). The conformation of both 5-membered lactone and furanose fused rings is also discussed.
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spelling pubmed-61470142018-11-19 Preparation Crystal Structure of (1S, 5S, 7S, 8R)-8-Hydroxy-7-phenyl-2,6-dioxabicyclo[3.3.0]octan-3-one Langer, Vratislav Gyepesová, Dalma Koman, Marian Kapitán, Peter Babjak, Matej Gracza, Tibor Koóš, Miroslav Molecules Article The absolute configuration at two newly formed stereogenic centres (5S, 7S) during the key steps of the total synthesis of naturally occuring goniothalesdiol was established by single-crystal X-ray diffraction analysis relative to stereocentres (1S, 8R) of the title compound (alternatively named 3,6-anhydro-2-deoxy-6-phenyl-l-ido-1,4-hexonolactone, C(12)H(12)O(4)). The conformation of both 5-membered lactone and furanose fused rings is also discussed. MDPI 2003-07-15 /pmc/articles/PMC6147014/ http://dx.doi.org/10.3390/80700599 Text en © 2003 by MDPI (http://www.mdpi.org). Reproduction is permitted for non commercial purposes.
spellingShingle Article
Langer, Vratislav
Gyepesová, Dalma
Koman, Marian
Kapitán, Peter
Babjak, Matej
Gracza, Tibor
Koóš, Miroslav
Preparation Crystal Structure of (1S, 5S, 7S, 8R)-8-Hydroxy-7-phenyl-2,6-dioxabicyclo[3.3.0]octan-3-one
title Preparation Crystal Structure of (1S, 5S, 7S, 8R)-8-Hydroxy-7-phenyl-2,6-dioxabicyclo[3.3.0]octan-3-one
title_full Preparation Crystal Structure of (1S, 5S, 7S, 8R)-8-Hydroxy-7-phenyl-2,6-dioxabicyclo[3.3.0]octan-3-one
title_fullStr Preparation Crystal Structure of (1S, 5S, 7S, 8R)-8-Hydroxy-7-phenyl-2,6-dioxabicyclo[3.3.0]octan-3-one
title_full_unstemmed Preparation Crystal Structure of (1S, 5S, 7S, 8R)-8-Hydroxy-7-phenyl-2,6-dioxabicyclo[3.3.0]octan-3-one
title_short Preparation Crystal Structure of (1S, 5S, 7S, 8R)-8-Hydroxy-7-phenyl-2,6-dioxabicyclo[3.3.0]octan-3-one
title_sort preparation crystal structure of (1s, 5s, 7s, 8r)-8-hydroxy-7-phenyl-2,6-dioxabicyclo[3.3.0]octan-3-one
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6147014/
http://dx.doi.org/10.3390/80700599
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