Synthesis and Catalytic Activity of Two New Cyclic Tetraaza Ligands

Two new chiral cyclic tetraaza ligands were synthesized and characterized. Their catalytic activity was tested in the asymmetric addition of diethylzinc to benzaldehyde. The expected secondary alcohol was obtained in moderate yields, but with very low enantioselectivity.

Detalles Bibliográficos
Autores principales: Fonseca, María Hechavarría, Hjelmgaard, Thomas, König, Burkhard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2003
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6147016/
http://dx.doi.org/10.3390/80500453
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author Fonseca, María Hechavarría
Hjelmgaard, Thomas
König, Burkhard
author_facet Fonseca, María Hechavarría
Hjelmgaard, Thomas
König, Burkhard
author_sort Fonseca, María Hechavarría
collection PubMed
description Two new chiral cyclic tetraaza ligands were synthesized and characterized. Their catalytic activity was tested in the asymmetric addition of diethylzinc to benzaldehyde. The expected secondary alcohol was obtained in moderate yields, but with very low enantioselectivity.
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spelling pubmed-61470162018-11-19 Synthesis and Catalytic Activity of Two New Cyclic Tetraaza Ligands Fonseca, María Hechavarría Hjelmgaard, Thomas König, Burkhard Molecules Article Two new chiral cyclic tetraaza ligands were synthesized and characterized. Their catalytic activity was tested in the asymmetric addition of diethylzinc to benzaldehyde. The expected secondary alcohol was obtained in moderate yields, but with very low enantioselectivity. MDPI 2003-05-31 /pmc/articles/PMC6147016/ http://dx.doi.org/10.3390/80500453 Text en © 2003 by MDPI (http://www.mdpi.org). Reproduction is permitted for noncommercial purposes.
spellingShingle Article
Fonseca, María Hechavarría
Hjelmgaard, Thomas
König, Burkhard
Synthesis and Catalytic Activity of Two New Cyclic Tetraaza Ligands
title Synthesis and Catalytic Activity of Two New Cyclic Tetraaza Ligands
title_full Synthesis and Catalytic Activity of Two New Cyclic Tetraaza Ligands
title_fullStr Synthesis and Catalytic Activity of Two New Cyclic Tetraaza Ligands
title_full_unstemmed Synthesis and Catalytic Activity of Two New Cyclic Tetraaza Ligands
title_short Synthesis and Catalytic Activity of Two New Cyclic Tetraaza Ligands
title_sort synthesis and catalytic activity of two new cyclic tetraaza ligands
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6147016/
http://dx.doi.org/10.3390/80500453
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AT hjelmgaardthomas synthesisandcatalyticactivityoftwonewcyclictetraazaligands
AT konigburkhard synthesisandcatalyticactivityoftwonewcyclictetraazaligands

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