A Facile Procedure for the Generation of Dichlorocarbene from the Reaction of Carbon Tetrachloride and Magnesium using Ultrasonic Irradiation

An improved method for the generation of dichlorocarbene was developed that utilizes ultrasound in the reaction of carbon tetrachloride with magnesium. High yields of gem-dichlorocyclopropane derivatives can be obtained in the presence of olefins by this method.

Detalles Bibliográficos
Autores principales: Lin, Haixia, Yang, Mingfa, Huang, Peigang, Cao, Weiguo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2003
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6147034/
http://dx.doi.org/10.3390/80800608
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author Lin, Haixia
Yang, Mingfa
Huang, Peigang
Cao, Weiguo
author_facet Lin, Haixia
Yang, Mingfa
Huang, Peigang
Cao, Weiguo
author_sort Lin, Haixia
collection PubMed
description An improved method for the generation of dichlorocarbene was developed that utilizes ultrasound in the reaction of carbon tetrachloride with magnesium. High yields of gem-dichlorocyclopropane derivatives can be obtained in the presence of olefins by this method.
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spelling pubmed-61470342018-11-19 A Facile Procedure for the Generation of Dichlorocarbene from the Reaction of Carbon Tetrachloride and Magnesium using Ultrasonic Irradiation Lin, Haixia Yang, Mingfa Huang, Peigang Cao, Weiguo Molecules Article An improved method for the generation of dichlorocarbene was developed that utilizes ultrasound in the reaction of carbon tetrachloride with magnesium. High yields of gem-dichlorocyclopropane derivatives can be obtained in the presence of olefins by this method. MDPI 2003-07-31 /pmc/articles/PMC6147034/ http://dx.doi.org/10.3390/80800608 Text en © 2003 by MDPI (http://www.mdpi.org). Reproduction is permitted for noncommercial purposes.
spellingShingle Article
Lin, Haixia
Yang, Mingfa
Huang, Peigang
Cao, Weiguo
A Facile Procedure for the Generation of Dichlorocarbene from the Reaction of Carbon Tetrachloride and Magnesium using Ultrasonic Irradiation
title A Facile Procedure for the Generation of Dichlorocarbene from the Reaction of Carbon Tetrachloride and Magnesium using Ultrasonic Irradiation
title_full A Facile Procedure for the Generation of Dichlorocarbene from the Reaction of Carbon Tetrachloride and Magnesium using Ultrasonic Irradiation
title_fullStr A Facile Procedure for the Generation of Dichlorocarbene from the Reaction of Carbon Tetrachloride and Magnesium using Ultrasonic Irradiation
title_full_unstemmed A Facile Procedure for the Generation of Dichlorocarbene from the Reaction of Carbon Tetrachloride and Magnesium using Ultrasonic Irradiation
title_short A Facile Procedure for the Generation of Dichlorocarbene from the Reaction of Carbon Tetrachloride and Magnesium using Ultrasonic Irradiation
title_sort facile procedure for the generation of dichlorocarbene from the reaction of carbon tetrachloride and magnesium using ultrasonic irradiation
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6147034/
http://dx.doi.org/10.3390/80800608
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