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Pd-Catalyzed Carbonyl Insertion Coupling Reactions of a Hypervalent Iodoheterocycle with Alcohols and Amines

The palladium-catalyzed cross-coupling carbonyl insertion reaction between 3,7-bis(N,N-dimethylamino)-10H-dibenz[b,e]iodinium iodide (1) and alcohols or amines 2 is described. Some new amides and esters 3 containing an active iodo functional group have been prepared in 65-91% yields.

Detalles Bibliográficos
Autores principales: Luo, Shengj-Jun, Ma, Yong-Xiang, Liang, Yong-Min
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2005
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6147542/
https://www.ncbi.nlm.nih.gov/pubmed/18007291
http://dx.doi.org/10.3390/10010238
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author Luo, Shengj-Jun
Ma, Yong-Xiang
Liang, Yong-Min
author_facet Luo, Shengj-Jun
Ma, Yong-Xiang
Liang, Yong-Min
author_sort Luo, Shengj-Jun
collection PubMed
description The palladium-catalyzed cross-coupling carbonyl insertion reaction between 3,7-bis(N,N-dimethylamino)-10H-dibenz[b,e]iodinium iodide (1) and alcohols or amines 2 is described. Some new amides and esters 3 containing an active iodo functional group have been prepared in 65-91% yields.
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spelling pubmed-61475422018-11-19 Pd-Catalyzed Carbonyl Insertion Coupling Reactions of a Hypervalent Iodoheterocycle with Alcohols and Amines Luo, Shengj-Jun Ma, Yong-Xiang Liang, Yong-Min Molecules Article The palladium-catalyzed cross-coupling carbonyl insertion reaction between 3,7-bis(N,N-dimethylamino)-10H-dibenz[b,e]iodinium iodide (1) and alcohols or amines 2 is described. Some new amides and esters 3 containing an active iodo functional group have been prepared in 65-91% yields. MDPI 2005-01-31 /pmc/articles/PMC6147542/ /pubmed/18007291 http://dx.doi.org/10.3390/10010238 Text en © 2005 by MDPI (http:www.mdpi.org). Reproduction is permitted for noncommercial purposes.
spellingShingle Article
Luo, Shengj-Jun
Ma, Yong-Xiang
Liang, Yong-Min
Pd-Catalyzed Carbonyl Insertion Coupling Reactions of a Hypervalent Iodoheterocycle with Alcohols and Amines
title Pd-Catalyzed Carbonyl Insertion Coupling Reactions of a Hypervalent Iodoheterocycle with Alcohols and Amines
title_full Pd-Catalyzed Carbonyl Insertion Coupling Reactions of a Hypervalent Iodoheterocycle with Alcohols and Amines
title_fullStr Pd-Catalyzed Carbonyl Insertion Coupling Reactions of a Hypervalent Iodoheterocycle with Alcohols and Amines
title_full_unstemmed Pd-Catalyzed Carbonyl Insertion Coupling Reactions of a Hypervalent Iodoheterocycle with Alcohols and Amines
title_short Pd-Catalyzed Carbonyl Insertion Coupling Reactions of a Hypervalent Iodoheterocycle with Alcohols and Amines
title_sort pd-catalyzed carbonyl insertion coupling reactions of a hypervalent iodoheterocycle with alcohols and amines
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6147542/
https://www.ncbi.nlm.nih.gov/pubmed/18007291
http://dx.doi.org/10.3390/10010238
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AT mayongxiang pdcatalyzedcarbonylinsertioncouplingreactionsofahypervalentiodoheterocyclewithalcoholsandamines
AT liangyongmin pdcatalyzedcarbonylinsertioncouplingreactionsofahypervalentiodoheterocyclewithalcoholsandamines