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Enantioselective Hydrogenations with Chiral Titanocenes

In this review article chiral titanocenes and their application for the enantioselective hydrogenations of different unsaturated compounds are discussed, with a special emphasis on the kinetics and the practicality of the developed systems. The nature of enantioselectivity and the hydrogenation mech...

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Detalles Bibliográficos
Autores principales: Vassylyev, Oleksiy, Panarello, Anthony, Khinast, Johannes G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2005
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6147634/
https://www.ncbi.nlm.nih.gov/pubmed/18007330
http://dx.doi.org/10.3390/10060587
Descripción
Sumario:In this review article chiral titanocenes and their application for the enantioselective hydrogenations of different unsaturated compounds are discussed, with a special emphasis on the kinetics and the practicality of the developed systems. The nature of enantioselectivity and the hydrogenation mechanisms are reviewed as well. Catalyst immobilization and the different immobilization techniques are examined.