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Structural Investigation of bis(4-Methyl-1-pipeqrazine- glyoximato)dipyridinato Cobalt(III) Chloro Dinitrate Trihydrate

The crystal and molecular structure of the title compound, C(24)H(36)CoN(10)O(4)·2(NO(3))·3(H(2)O)·Cl, have been determined by X-ray analysis: Cc (No: 9), a = 17.6920(4) Å, b = 11.8163(2) Å, c = 16.4752(4) Å, ß = 91.679(1)°, Z = 4. The Co(III) ion is six-coordinated with octahedral geometry, the pyr...

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Detalles Bibliográficos
Autores principales: Öztürk, Sema, Akkurt, Mehmet, Macit, Mustafa, Işık, Şamil, Fun, Hoong Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2005
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6147645/
https://www.ncbi.nlm.nih.gov/pubmed/18007345
http://dx.doi.org/10.3390/10070767
Descripción
Sumario:The crystal and molecular structure of the title compound, C(24)H(36)CoN(10)O(4)·2(NO(3))·3(H(2)O)·Cl, have been determined by X-ray analysis: Cc (No: 9), a = 17.6920(4) Å, b = 11.8163(2) Å, c = 16.4752(4) Å, ß = 91.679(1)°, Z = 4. The Co(III) ion is six-coordinated with octahedral geometry, the pyridine rings are planar and the piperazine rings assume chair conformations.