Addition to Electron Deficient Olefins of α-Oxy Carbon- Centered Radicals, Generated from Cyclic Ethers and Acetals by the Reaction with Alkylperoxy- λ(3)-iodane

Thermal decomposition of 1-tert-butylperoxy-1,2-benziodoxol-3(1H)-one in cyclic ethers and acetals at 50 °C generates α-oxy carbon-centered radicals, which undergo an addition reaction with vinyl sulfones and unsaturated esters.

Detalles Bibliográficos
Autores principales: Sueda, Takuya, Takeuchi, Yasunori, Suefuji, Takashi, Ochiai, Masahito
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2005
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6147646/
https://www.ncbi.nlm.nih.gov/pubmed/18007287
http://dx.doi.org/10.3390/10010195
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author Sueda, Takuya
Takeuchi, Yasunori
Suefuji, Takashi
Ochiai, Masahito
author_facet Sueda, Takuya
Takeuchi, Yasunori
Suefuji, Takashi
Ochiai, Masahito
author_sort Sueda, Takuya
collection PubMed
description Thermal decomposition of 1-tert-butylperoxy-1,2-benziodoxol-3(1H)-one in cyclic ethers and acetals at 50 °C generates α-oxy carbon-centered radicals, which undergo an addition reaction with vinyl sulfones and unsaturated esters.
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spelling pubmed-61476462018-11-19 Addition to Electron Deficient Olefins of α-Oxy Carbon- Centered Radicals, Generated from Cyclic Ethers and Acetals by the Reaction with Alkylperoxy- λ(3)-iodane Sueda, Takuya Takeuchi, Yasunori Suefuji, Takashi Ochiai, Masahito Molecules Article Thermal decomposition of 1-tert-butylperoxy-1,2-benziodoxol-3(1H)-one in cyclic ethers and acetals at 50 °C generates α-oxy carbon-centered radicals, which undergo an addition reaction with vinyl sulfones and unsaturated esters. MDPI 2005-01-31 /pmc/articles/PMC6147646/ /pubmed/18007287 http://dx.doi.org/10.3390/10010195 Text en © 2005 by MDPI (http://www.mdpi.org). Reproduction is permitted for noncommercial purposes.
spellingShingle Article
Sueda, Takuya
Takeuchi, Yasunori
Suefuji, Takashi
Ochiai, Masahito
Addition to Electron Deficient Olefins of α-Oxy Carbon- Centered Radicals, Generated from Cyclic Ethers and Acetals by the Reaction with Alkylperoxy- λ(3)-iodane
title Addition to Electron Deficient Olefins of α-Oxy Carbon- Centered Radicals, Generated from Cyclic Ethers and Acetals by the Reaction with Alkylperoxy- λ(3)-iodane
title_full Addition to Electron Deficient Olefins of α-Oxy Carbon- Centered Radicals, Generated from Cyclic Ethers and Acetals by the Reaction with Alkylperoxy- λ(3)-iodane
title_fullStr Addition to Electron Deficient Olefins of α-Oxy Carbon- Centered Radicals, Generated from Cyclic Ethers and Acetals by the Reaction with Alkylperoxy- λ(3)-iodane
title_full_unstemmed Addition to Electron Deficient Olefins of α-Oxy Carbon- Centered Radicals, Generated from Cyclic Ethers and Acetals by the Reaction with Alkylperoxy- λ(3)-iodane
title_short Addition to Electron Deficient Olefins of α-Oxy Carbon- Centered Radicals, Generated from Cyclic Ethers and Acetals by the Reaction with Alkylperoxy- λ(3)-iodane
title_sort addition to electron deficient olefins of α-oxy carbon- centered radicals, generated from cyclic ethers and acetals by the reaction with alkylperoxy- λ(3)-iodane
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6147646/
https://www.ncbi.nlm.nih.gov/pubmed/18007287
http://dx.doi.org/10.3390/10010195
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