A Novel Aromatic Iodination Method, with Sodium Periodate Used as the Only Iodinating Reagent†

Benzene, halobenzenes and some deactivated arenes readily reacted in anhydrous NaIO(4)/AcOH/Ac(2)O/concd. H(2)SO(4) mixtures to afford, after quenching with excess aqueous Na(2)SO(3) solution (a reducing agent), purified iodinated products in 27-88% yields. This novel method of aromatic iodination i...

Descripción completa

Detalles Bibliográficos
Autores principales: Luliński, Piotr, Sosnowski, Maciej, Skulski, Lech
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2005
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6147649/
https://www.ncbi.nlm.nih.gov/pubmed/18007324
http://dx.doi.org/10.3390/10030516
_version_ 1783356595813482496
author Luliński, Piotr
Sosnowski, Maciej
Skulski, Lech
author_facet Luliński, Piotr
Sosnowski, Maciej
Skulski, Lech
author_sort Luliński, Piotr
collection PubMed
description Benzene, halobenzenes and some deactivated arenes readily reacted in anhydrous NaIO(4)/AcOH/Ac(2)O/concd. H(2)SO(4) mixtures to afford, after quenching with excess aqueous Na(2)SO(3) solution (a reducing agent), purified iodinated products in 27-88% yields. This novel method of aromatic iodination is simple, fairly effective and environmentally safe.
format Online
Article
Text
id pubmed-6147649
institution National Center for Biotechnology Information
language English
publishDate 2005
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-61476492018-11-19 A Novel Aromatic Iodination Method, with Sodium Periodate Used as the Only Iodinating Reagent† Luliński, Piotr Sosnowski, Maciej Skulski, Lech Molecules Article Benzene, halobenzenes and some deactivated arenes readily reacted in anhydrous NaIO(4)/AcOH/Ac(2)O/concd. H(2)SO(4) mixtures to afford, after quenching with excess aqueous Na(2)SO(3) solution (a reducing agent), purified iodinated products in 27-88% yields. This novel method of aromatic iodination is simple, fairly effective and environmentally safe. MDPI 2005-05-13 /pmc/articles/PMC6147649/ /pubmed/18007324 http://dx.doi.org/10.3390/10030516 Text en © 2005 by MDPI (http://www.mdpi.org). Reproduction is permitted for noncommercial purposes.
spellingShingle Article
Luliński, Piotr
Sosnowski, Maciej
Skulski, Lech
A Novel Aromatic Iodination Method, with Sodium Periodate Used as the Only Iodinating Reagent†
title A Novel Aromatic Iodination Method, with Sodium Periodate Used as the Only Iodinating Reagent†
title_full A Novel Aromatic Iodination Method, with Sodium Periodate Used as the Only Iodinating Reagent†
title_fullStr A Novel Aromatic Iodination Method, with Sodium Periodate Used as the Only Iodinating Reagent†
title_full_unstemmed A Novel Aromatic Iodination Method, with Sodium Periodate Used as the Only Iodinating Reagent†
title_short A Novel Aromatic Iodination Method, with Sodium Periodate Used as the Only Iodinating Reagent†
title_sort novel aromatic iodination method, with sodium periodate used as the only iodinating reagent†
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6147649/
https://www.ncbi.nlm.nih.gov/pubmed/18007324
http://dx.doi.org/10.3390/10030516
work_keys_str_mv AT lulinskipiotr anovelaromaticiodinationmethodwithsodiumperiodateusedastheonlyiodinatingreagent
AT sosnowskimaciej anovelaromaticiodinationmethodwithsodiumperiodateusedastheonlyiodinatingreagent
AT skulskilech anovelaromaticiodinationmethodwithsodiumperiodateusedastheonlyiodinatingreagent
AT lulinskipiotr novelaromaticiodinationmethodwithsodiumperiodateusedastheonlyiodinatingreagent
AT sosnowskimaciej novelaromaticiodinationmethodwithsodiumperiodateusedastheonlyiodinatingreagent
AT skulskilech novelaromaticiodinationmethodwithsodiumperiodateusedastheonlyiodinatingreagent

Ejemplares similares