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A New iso-Amyl Benzothiazolyl Sulfoxide as an Extractant for Palladium the Crystal Structure of its Palladium (II) Complex
A new iso-amyl benzothiazolyl sulfoxide (ABSO) was synthesized and used in the extraction of Pd(II) from hydrochloric acid media. Pd(II) was extracted quantitatively from 0.1 M HCl with ABSO in benzene (0.5 M). Ammonia solution (2.0 M) could be used as stripping agent. ABSO and Pd(II) form a 2:1 add...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2005
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6147664/ https://www.ncbi.nlm.nih.gov/pubmed/18007360 http://dx.doi.org/10.3390/10080912 |
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author | Li, Yao-Wei Gu, Guo-Bang Liu, Hai-Yang Sung, Herman H. Y. Williams, Ian D. Chang, Chi-K. |
author_facet | Li, Yao-Wei Gu, Guo-Bang Liu, Hai-Yang Sung, Herman H. Y. Williams, Ian D. Chang, Chi-K. |
author_sort | Li, Yao-Wei |
collection | PubMed |
description | A new iso-amyl benzothiazolyl sulfoxide (ABSO) was synthesized and used in the extraction of Pd(II) from hydrochloric acid media. Pd(II) was extracted quantitatively from 0.1 M HCl with ABSO in benzene (0.5 M). Ammonia solution (2.0 M) could be used as stripping agent. ABSO and Pd(II) form a 2:1 adduct [Pd (ABSO)(2)Cl(2)] in the extraction. X-ray crystal structure determination revealed PdCl(2)(ABSO)(2) is a square-planar complex in which ABSO acts as a neutral unidentate ligand coordinated with palladium(II) via the thiazolyl N atom. |
format | Online Article Text |
id | pubmed-6147664 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2005 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-61476642018-11-19 A New iso-Amyl Benzothiazolyl Sulfoxide as an Extractant for Palladium the Crystal Structure of its Palladium (II) Complex Li, Yao-Wei Gu, Guo-Bang Liu, Hai-Yang Sung, Herman H. Y. Williams, Ian D. Chang, Chi-K. Molecules Article A new iso-amyl benzothiazolyl sulfoxide (ABSO) was synthesized and used in the extraction of Pd(II) from hydrochloric acid media. Pd(II) was extracted quantitatively from 0.1 M HCl with ABSO in benzene (0.5 M). Ammonia solution (2.0 M) could be used as stripping agent. ABSO and Pd(II) form a 2:1 adduct [Pd (ABSO)(2)Cl(2)] in the extraction. X-ray crystal structure determination revealed PdCl(2)(ABSO)(2) is a square-planar complex in which ABSO acts as a neutral unidentate ligand coordinated with palladium(II) via the thiazolyl N atom. MDPI 2005-08-31 /pmc/articles/PMC6147664/ /pubmed/18007360 http://dx.doi.org/10.3390/10080912 Text en © 2005 by MDPI (http://www.mdpi.org). Reproduction is permitted for noncommercial purposes. |
spellingShingle | Article Li, Yao-Wei Gu, Guo-Bang Liu, Hai-Yang Sung, Herman H. Y. Williams, Ian D. Chang, Chi-K. A New iso-Amyl Benzothiazolyl Sulfoxide as an Extractant for Palladium the Crystal Structure of its Palladium (II) Complex |
title | A New iso-Amyl Benzothiazolyl Sulfoxide as an Extractant for Palladium the Crystal Structure of its Palladium (II) Complex |
title_full | A New iso-Amyl Benzothiazolyl Sulfoxide as an Extractant for Palladium the Crystal Structure of its Palladium (II) Complex |
title_fullStr | A New iso-Amyl Benzothiazolyl Sulfoxide as an Extractant for Palladium the Crystal Structure of its Palladium (II) Complex |
title_full_unstemmed | A New iso-Amyl Benzothiazolyl Sulfoxide as an Extractant for Palladium the Crystal Structure of its Palladium (II) Complex |
title_short | A New iso-Amyl Benzothiazolyl Sulfoxide as an Extractant for Palladium the Crystal Structure of its Palladium (II) Complex |
title_sort | new iso-amyl benzothiazolyl sulfoxide as an extractant for palladium the crystal structure of its palladium (ii) complex |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6147664/ https://www.ncbi.nlm.nih.gov/pubmed/18007360 http://dx.doi.org/10.3390/10080912 |
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