A New iso-Amyl Benzothiazolyl Sulfoxide as an Extractant for Palladium the Crystal Structure of its Palladium (II) Complex

A new iso-amyl benzothiazolyl sulfoxide (ABSO) was synthesized and used in the extraction of Pd(II) from hydrochloric acid media. Pd(II) was extracted quantitatively from 0.1 M HCl with ABSO in benzene (0.5 M). Ammonia solution (2.0 M) could be used as stripping agent. ABSO and Pd(II) form a 2:1 add...

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Detalles Bibliográficos
Autores principales: Li, Yao-Wei, Gu, Guo-Bang, Liu, Hai-Yang, Sung, Herman H. Y., Williams, Ian D., Chang, Chi-K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2005
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6147664/
https://www.ncbi.nlm.nih.gov/pubmed/18007360
http://dx.doi.org/10.3390/10080912
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author Li, Yao-Wei
Gu, Guo-Bang
Liu, Hai-Yang
Sung, Herman H. Y.
Williams, Ian D.
Chang, Chi-K.
author_facet Li, Yao-Wei
Gu, Guo-Bang
Liu, Hai-Yang
Sung, Herman H. Y.
Williams, Ian D.
Chang, Chi-K.
author_sort Li, Yao-Wei
collection PubMed
description A new iso-amyl benzothiazolyl sulfoxide (ABSO) was synthesized and used in the extraction of Pd(II) from hydrochloric acid media. Pd(II) was extracted quantitatively from 0.1 M HCl with ABSO in benzene (0.5 M). Ammonia solution (2.0 M) could be used as stripping agent. ABSO and Pd(II) form a 2:1 adduct [Pd (ABSO)(2)Cl(2)] in the extraction. X-ray crystal structure determination revealed PdCl(2)(ABSO)(2) is a square-planar complex in which ABSO acts as a neutral unidentate ligand coordinated with palladium(II) via the thiazolyl N atom.
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spelling pubmed-61476642018-11-19 A New iso-Amyl Benzothiazolyl Sulfoxide as an Extractant for Palladium the Crystal Structure of its Palladium (II) Complex Li, Yao-Wei Gu, Guo-Bang Liu, Hai-Yang Sung, Herman H. Y. Williams, Ian D. Chang, Chi-K. Molecules Article A new iso-amyl benzothiazolyl sulfoxide (ABSO) was synthesized and used in the extraction of Pd(II) from hydrochloric acid media. Pd(II) was extracted quantitatively from 0.1 M HCl with ABSO in benzene (0.5 M). Ammonia solution (2.0 M) could be used as stripping agent. ABSO and Pd(II) form a 2:1 adduct [Pd (ABSO)(2)Cl(2)] in the extraction. X-ray crystal structure determination revealed PdCl(2)(ABSO)(2) is a square-planar complex in which ABSO acts as a neutral unidentate ligand coordinated with palladium(II) via the thiazolyl N atom. MDPI 2005-08-31 /pmc/articles/PMC6147664/ /pubmed/18007360 http://dx.doi.org/10.3390/10080912 Text en © 2005 by MDPI (http://www.mdpi.org). Reproduction is permitted for noncommercial purposes.
spellingShingle Article
Li, Yao-Wei
Gu, Guo-Bang
Liu, Hai-Yang
Sung, Herman H. Y.
Williams, Ian D.
Chang, Chi-K.
A New iso-Amyl Benzothiazolyl Sulfoxide as an Extractant for Palladium the Crystal Structure of its Palladium (II) Complex
title A New iso-Amyl Benzothiazolyl Sulfoxide as an Extractant for Palladium the Crystal Structure of its Palladium (II) Complex
title_full A New iso-Amyl Benzothiazolyl Sulfoxide as an Extractant for Palladium the Crystal Structure of its Palladium (II) Complex
title_fullStr A New iso-Amyl Benzothiazolyl Sulfoxide as an Extractant for Palladium the Crystal Structure of its Palladium (II) Complex
title_full_unstemmed A New iso-Amyl Benzothiazolyl Sulfoxide as an Extractant for Palladium the Crystal Structure of its Palladium (II) Complex
title_short A New iso-Amyl Benzothiazolyl Sulfoxide as an Extractant for Palladium the Crystal Structure of its Palladium (II) Complex
title_sort new iso-amyl benzothiazolyl sulfoxide as an extractant for palladium the crystal structure of its palladium (ii) complex
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6147664/
https://www.ncbi.nlm.nih.gov/pubmed/18007360
http://dx.doi.org/10.3390/10080912
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