1,3-Dipolar Cycloaddition Reactions of 1-(4-Phenylphenacyl)-1,10-phenanthrolinium N-Ylide with Activated Alkynes and Alkenes

The 3+2 cycloaddition reaction of 1-(4-phenylphenacyl)-1,10-phenanthrolinium ylide 4 with activated alkynes gave pyrrolo[1,2-a][1,10]phenanthrolines 6a-d. The "one pot" synthesis of 6a,b,d from 4, activated alkenes, Et(3)N and tetrakis-pyridine cobalt (II) dichromate (TPCD) is described. T...

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Detalles Bibliográficos
Autores principales: Dumitrascu, Alkenes F., Caira, M. R., Draghici, C., Caproiu, M. T., Badoiu, A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2005
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6147677/
https://www.ncbi.nlm.nih.gov/pubmed/18007302
http://dx.doi.org/10.3390/10020321
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author Dumitrascu, Alkenes F.
Caira, M. R.
Draghici, C.
Caproiu, M. T.
Badoiu, A.
author_facet Dumitrascu, Alkenes F.
Caira, M. R.
Draghici, C.
Caproiu, M. T.
Badoiu, A.
author_sort Dumitrascu, Alkenes F.
collection PubMed
description The 3+2 cycloaddition reaction of 1-(4-phenylphenacyl)-1,10-phenanthrolinium ylide 4 with activated alkynes gave pyrrolo[1,2-a][1,10]phenanthrolines 6a-d. The "one pot" synthesis of 6a,b,d from 4, activated alkenes, Et(3)N and tetrakis-pyridine cobalt (II) dichromate (TPCD) is described. The helical chirality of pyrrolophenanthrolines 6b-d was put in evidence by NMR spectroscopy.
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spelling pubmed-61476772018-11-19 1,3-Dipolar Cycloaddition Reactions of 1-(4-Phenylphenacyl)-1,10-phenanthrolinium N-Ylide with Activated Alkynes and Alkenes Dumitrascu, Alkenes F. Caira, M. R. Draghici, C. Caproiu, M. T. Badoiu, A. Molecules Article The 3+2 cycloaddition reaction of 1-(4-phenylphenacyl)-1,10-phenanthrolinium ylide 4 with activated alkynes gave pyrrolo[1,2-a][1,10]phenanthrolines 6a-d. The "one pot" synthesis of 6a,b,d from 4, activated alkenes, Et(3)N and tetrakis-pyridine cobalt (II) dichromate (TPCD) is described. The helical chirality of pyrrolophenanthrolines 6b-d was put in evidence by NMR spectroscopy. MDPI 2005-02-28 /pmc/articles/PMC6147677/ /pubmed/18007302 http://dx.doi.org/10.3390/10020321 Text en © 2005 by MDPI (http://www.mdpi.org). Reproduction is permitted for noncommercial purposes.
spellingShingle Article
Dumitrascu, Alkenes F.
Caira, M. R.
Draghici, C.
Caproiu, M. T.
Badoiu, A.
1,3-Dipolar Cycloaddition Reactions of 1-(4-Phenylphenacyl)-1,10-phenanthrolinium N-Ylide with Activated Alkynes and Alkenes
title 1,3-Dipolar Cycloaddition Reactions of 1-(4-Phenylphenacyl)-1,10-phenanthrolinium N-Ylide with Activated Alkynes and Alkenes
title_full 1,3-Dipolar Cycloaddition Reactions of 1-(4-Phenylphenacyl)-1,10-phenanthrolinium N-Ylide with Activated Alkynes and Alkenes
title_fullStr 1,3-Dipolar Cycloaddition Reactions of 1-(4-Phenylphenacyl)-1,10-phenanthrolinium N-Ylide with Activated Alkynes and Alkenes
title_full_unstemmed 1,3-Dipolar Cycloaddition Reactions of 1-(4-Phenylphenacyl)-1,10-phenanthrolinium N-Ylide with Activated Alkynes and Alkenes
title_short 1,3-Dipolar Cycloaddition Reactions of 1-(4-Phenylphenacyl)-1,10-phenanthrolinium N-Ylide with Activated Alkynes and Alkenes
title_sort 1,3-dipolar cycloaddition reactions of 1-(4-phenylphenacyl)-1,10-phenanthrolinium n-ylide with activated alkynes and alkenes
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6147677/
https://www.ncbi.nlm.nih.gov/pubmed/18007302
http://dx.doi.org/10.3390/10020321
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