Oxidative Dearomatization of Phenols and Anilines via λ(3)- and λ(5)-Iodane-Mediated Phenylation and Oxygenation

Treatment of 2-methylphenols with chloro(diphenyl)-λ(3)-iodane led to their regioselective dearomatizing 2-phenylation into cyclohexa-2,4-dienone derivatives via a proposed ligand coupling reaction. In the same vein of investigation, treatment of 2-methylanilines with the λ(5)-iodane 2-iodoxybenzoic...

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Autores principales: Quideau, Stéphane, Pouységu, Laurent, Ozanne, Aurélie, Gagnepain, Julien
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2005
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6147688/
https://www.ncbi.nlm.nih.gov/pubmed/18007288
http://dx.doi.org/10.3390/10010201
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author Quideau, Stéphane
Pouységu, Laurent
Ozanne, Aurélie
Gagnepain, Julien
author_facet Quideau, Stéphane
Pouységu, Laurent
Ozanne, Aurélie
Gagnepain, Julien
author_sort Quideau, Stéphane
collection PubMed
description Treatment of 2-methylphenols with chloro(diphenyl)-λ(3)-iodane led to their regioselective dearomatizing 2-phenylation into cyclohexa-2,4-dienone derivatives via a proposed ligand coupling reaction. In the same vein of investigation, treatment of 2-methylanilines with the λ(5)-iodane 2-iodoxybenzoic acid IBX reagent led to their regioselective dearomatization into previously undescribed ortho-quinol imines.
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spelling pubmed-61476882018-11-19 Oxidative Dearomatization of Phenols and Anilines via λ(3)- and λ(5)-Iodane-Mediated Phenylation and Oxygenation Quideau, Stéphane Pouységu, Laurent Ozanne, Aurélie Gagnepain, Julien Molecules Article Treatment of 2-methylphenols with chloro(diphenyl)-λ(3)-iodane led to their regioselective dearomatizing 2-phenylation into cyclohexa-2,4-dienone derivatives via a proposed ligand coupling reaction. In the same vein of investigation, treatment of 2-methylanilines with the λ(5)-iodane 2-iodoxybenzoic acid IBX reagent led to their regioselective dearomatization into previously undescribed ortho-quinol imines. MDPI 2005-01-31 /pmc/articles/PMC6147688/ /pubmed/18007288 http://dx.doi.org/10.3390/10010201 Text en © 2005 by MDPI (http://www.mdpi.org). Reproduction is permitted for noncommercial purposes.
spellingShingle Article
Quideau, Stéphane
Pouységu, Laurent
Ozanne, Aurélie
Gagnepain, Julien
Oxidative Dearomatization of Phenols and Anilines via λ(3)- and λ(5)-Iodane-Mediated Phenylation and Oxygenation
title Oxidative Dearomatization of Phenols and Anilines via λ(3)- and λ(5)-Iodane-Mediated Phenylation and Oxygenation
title_full Oxidative Dearomatization of Phenols and Anilines via λ(3)- and λ(5)-Iodane-Mediated Phenylation and Oxygenation
title_fullStr Oxidative Dearomatization of Phenols and Anilines via λ(3)- and λ(5)-Iodane-Mediated Phenylation and Oxygenation
title_full_unstemmed Oxidative Dearomatization of Phenols and Anilines via λ(3)- and λ(5)-Iodane-Mediated Phenylation and Oxygenation
title_short Oxidative Dearomatization of Phenols and Anilines via λ(3)- and λ(5)-Iodane-Mediated Phenylation and Oxygenation
title_sort oxidative dearomatization of phenols and anilines via λ(3)- and λ(5)-iodane-mediated phenylation and oxygenation
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6147688/
https://www.ncbi.nlm.nih.gov/pubmed/18007288
http://dx.doi.org/10.3390/10010201
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