Triisobutylaluminium (TIBAL) Promoted Rearrangement of C-glycosides

Triisobutylaluminium-promoted rearrangement of unsaturated glycosides containing electron-donating aglycons, such as C-aryl glycosides, provides direct access to highly functionalised cyclohexane derivatives.

Detalles Bibliográficos
Autores principales: Sollogoub, Matthieu, Sinaÿ, Pierre
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2005
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6147693/
https://www.ncbi.nlm.nih.gov/pubmed/18007354
http://dx.doi.org/10.3390/10080843
Descripción
Sumario:Triisobutylaluminium-promoted rearrangement of unsaturated glycosides containing electron-donating aglycons, such as C-aryl glycosides, provides direct access to highly functionalised cyclohexane derivatives.

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