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The 5-Endo-trig Cyclization of d-Glucose Derived γ-Alkenylamines with Mercury (II) Salts: Synthesis of 1-Deoxy-castanospermine and its 8a-epi-Analogue†
The intramolecular aminomercuration of γ-alkenylamines 1a, 1b and 4 was shown to afford the 5-endo-trig cyclized product exclusively in good yield. The utility of pyrrolidine derivatives thus obtained from D-glucose derived γ-alkenylamines 1a and 1b was demonstrated in the synthesis of 1-deoxycastan...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2005
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6147711/ https://www.ncbi.nlm.nih.gov/pubmed/18007358 http://dx.doi.org/10.3390/10080893 |