Bi(OTf)(3) and SiO(2)-Bi(OTf)(3) as Effective Catalysts for the Ferrier Rearrangement#

Bi(OTf)(3) and SiO(2)-Bi(OTf)(3) are found to effectively catalyze the Ferrier rearrangement of tri-O-acetyl glycals with different alcohols providing an effective route to 2,3-unsaturated O-glycosides with good anomeric selectivity and  good to excellent yields after short reaction times.

Detalles Bibliográficos
Autores principales: Babu, J. Lokesh, Khare, Anakshi, Vankar, Yashwant D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2005
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6147713/
https://www.ncbi.nlm.nih.gov/pubmed/18007357
http://dx.doi.org/10.3390/10080884
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author Babu, J. Lokesh
Khare, Anakshi
Vankar, Yashwant D.
author_facet Babu, J. Lokesh
Khare, Anakshi
Vankar, Yashwant D.
author_sort Babu, J. Lokesh
collection PubMed
description Bi(OTf)(3) and SiO(2)-Bi(OTf)(3) are found to effectively catalyze the Ferrier rearrangement of tri-O-acetyl glycals with different alcohols providing an effective route to 2,3-unsaturated O-glycosides with good anomeric selectivity and  good to excellent yields after short reaction times.
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spelling pubmed-61477132018-11-19 Bi(OTf)(3) and SiO(2)-Bi(OTf)(3) as Effective Catalysts for the Ferrier Rearrangement# Babu, J. Lokesh Khare, Anakshi Vankar, Yashwant D. Molecules Article Bi(OTf)(3) and SiO(2)-Bi(OTf)(3) are found to effectively catalyze the Ferrier rearrangement of tri-O-acetyl glycals with different alcohols providing an effective route to 2,3-unsaturated O-glycosides with good anomeric selectivity and  good to excellent yields after short reaction times. MDPI 2005-08-31 /pmc/articles/PMC6147713/ /pubmed/18007357 http://dx.doi.org/10.3390/10080884 Text en © 2005 by MDPI (http://www.mdpi.org). Reproduction is permitted for non commercial purposes.
spellingShingle Article
Babu, J. Lokesh
Khare, Anakshi
Vankar, Yashwant D.
Bi(OTf)(3) and SiO(2)-Bi(OTf)(3) as Effective Catalysts for the Ferrier Rearrangement#
title Bi(OTf)(3) and SiO(2)-Bi(OTf)(3) as Effective Catalysts for the Ferrier Rearrangement#
title_full Bi(OTf)(3) and SiO(2)-Bi(OTf)(3) as Effective Catalysts for the Ferrier Rearrangement#
title_fullStr Bi(OTf)(3) and SiO(2)-Bi(OTf)(3) as Effective Catalysts for the Ferrier Rearrangement#
title_full_unstemmed Bi(OTf)(3) and SiO(2)-Bi(OTf)(3) as Effective Catalysts for the Ferrier Rearrangement#
title_short Bi(OTf)(3) and SiO(2)-Bi(OTf)(3) as Effective Catalysts for the Ferrier Rearrangement#
title_sort bi(otf)(3) and sio(2)-bi(otf)(3) as effective catalysts for the ferrier rearrangement#
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6147713/
https://www.ncbi.nlm.nih.gov/pubmed/18007357
http://dx.doi.org/10.3390/10080884
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AT khareanakshi biotf3andsio2biotf3aseffectivecatalystsfortheferrierrearrangement
AT vankaryashwantd biotf3andsio2biotf3aseffectivecatalystsfortheferrierrearrangement

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