A mild light-induced cleavage of the S–O bond of aryl sulfonate esters enables efficient sulfonylation of vinylarenes

A new mode of S–O bond activation has been discovered, which constitutes novel reactivity of easily available and bench-stable arylsulfonate phenol esters. This protocol enables access to putative sulfonyl radical intermediates, which enable straightforward access to valuable vinyl sulfones.

Detalles Bibliográficos
Autores principales: Ratushnyy, Maxim, Kamenova, Monika, Gevorgyan, Vladimir
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6148202/
https://www.ncbi.nlm.nih.gov/pubmed/30288238
http://dx.doi.org/10.1039/c8sc02769b
_version_ 1783356719112388608
author Ratushnyy, Maxim
Kamenova, Monika
Gevorgyan, Vladimir
author_facet Ratushnyy, Maxim
Kamenova, Monika
Gevorgyan, Vladimir
author_sort Ratushnyy, Maxim
collection PubMed
description A new mode of S–O bond activation has been discovered, which constitutes novel reactivity of easily available and bench-stable arylsulfonate phenol esters. This protocol enables access to putative sulfonyl radical intermediates, which enable straightforward access to valuable vinyl sulfones.
format Online
Article
Text
id pubmed-6148202
institution National Center for Biotechnology Information
language English
publishDate 2018
publisher Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-61482022018-10-04 A mild light-induced cleavage of the S–O bond of aryl sulfonate esters enables efficient sulfonylation of vinylarenes Ratushnyy, Maxim Kamenova, Monika Gevorgyan, Vladimir Chem Sci Chemistry A new mode of S–O bond activation has been discovered, which constitutes novel reactivity of easily available and bench-stable arylsulfonate phenol esters. This protocol enables access to putative sulfonyl radical intermediates, which enable straightforward access to valuable vinyl sulfones. Royal Society of Chemistry 2018-07-25 /pmc/articles/PMC6148202/ /pubmed/30288238 http://dx.doi.org/10.1039/c8sc02769b Text en This journal is © The Royal Society of Chemistry 2018 http://creativecommons.org/licenses/by-nc/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution Non Commercial 3.0 Unported Licence (CC BY-NC 3.0)
spellingShingle Chemistry
Ratushnyy, Maxim
Kamenova, Monika
Gevorgyan, Vladimir
A mild light-induced cleavage of the S–O bond of aryl sulfonate esters enables efficient sulfonylation of vinylarenes
title A mild light-induced cleavage of the S–O bond of aryl sulfonate esters enables efficient sulfonylation of vinylarenes
title_full A mild light-induced cleavage of the S–O bond of aryl sulfonate esters enables efficient sulfonylation of vinylarenes
title_fullStr A mild light-induced cleavage of the S–O bond of aryl sulfonate esters enables efficient sulfonylation of vinylarenes
title_full_unstemmed A mild light-induced cleavage of the S–O bond of aryl sulfonate esters enables efficient sulfonylation of vinylarenes
title_short A mild light-induced cleavage of the S–O bond of aryl sulfonate esters enables efficient sulfonylation of vinylarenes
title_sort mild light-induced cleavage of the s–o bond of aryl sulfonate esters enables efficient sulfonylation of vinylarenes
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6148202/
https://www.ncbi.nlm.nih.gov/pubmed/30288238
http://dx.doi.org/10.1039/c8sc02769b
work_keys_str_mv AT ratushnyymaxim amildlightinducedcleavageofthesobondofarylsulfonateestersenablesefficientsulfonylationofvinylarenes
AT kamenovamonika amildlightinducedcleavageofthesobondofarylsulfonateestersenablesefficientsulfonylationofvinylarenes
AT gevorgyanvladimir amildlightinducedcleavageofthesobondofarylsulfonateestersenablesefficientsulfonylationofvinylarenes
AT ratushnyymaxim mildlightinducedcleavageofthesobondofarylsulfonateestersenablesefficientsulfonylationofvinylarenes
AT kamenovamonika mildlightinducedcleavageofthesobondofarylsulfonateestersenablesefficientsulfonylationofvinylarenes
AT gevorgyanvladimir mildlightinducedcleavageofthesobondofarylsulfonateestersenablesefficientsulfonylationofvinylarenes

Ejemplares similares