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Synthesis of TiO(2) with Hierarchical Porosity for the Photooxidation of Propene

The elimination of volatile organic compounds (VOCs) at low concentration is a subject of great interest because these compounds are very harmful for the environment and human health. In this work, we have developed a synthesis methodology of TiO(2) that allows obtaining meso-macroporous materials w...

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Detalles Bibliográficos
Autores principales: Fernández-Catalá, Javier, Cano-Casanova, Laura, Lillo-Ródenas, María Ángeles, Berenguer-Murcia, Ángel, Cazorla-Amorós, Diego
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6149674/
https://www.ncbi.nlm.nih.gov/pubmed/29258171
http://dx.doi.org/10.3390/molecules22122243
Descripción
Sumario:The elimination of volatile organic compounds (VOCs) at low concentration is a subject of great interest because these compounds are very harmful for the environment and human health. In this work, we have developed a synthesis methodology of TiO(2) that allows obtaining meso-macroporous materials with hierarchical porosity and with high thermal stability for their application as photocatalysts in the removal of VOCs, specifically propene. The materials synthesized in this work were characterized by Scanning electron microscope (SEM), Transmission electron microscopy (TEM), powder X-ray diffraction (XRD), Thermogravimetric Analysis (TG), and nitrogen adsorption. It is observed that the samples calcined at 250 °C and 500 °C present a high photoactivity for the photooxidation of propene, which is similar to the benchmark material P25 (commercial TiO(2)). Moreover, the textural properties are better than those for P25, indicating that the samples are interesting for the preparation of photocatalysts with different conformations, such as in the form of coatings and fillings in different size scales.